The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Chroustchoff obtained it directly from soluble
silica. Thus this hydrate is able to form not only the variety
having the specific gravity 2·2 but also the more stable variety
of sp. gr. 2·6; and both exist with a small proportion of water
and in a perfectly anhydrous state in an amorphous and crystalline
form. All these facts are expressed by recognising silica as
dimorphous, and their cause must be looked for in a difference in
the degree of polymerisation.
[14] Deposits of perfectly white tripoli have been discovered near
Batoum, and might prove of some commercial importance.
[14 bis] Alkaline solutions, saturated with silica and known as _soluble
glass_, are prepared on a large scale for technical purposes by
the action of potassium (or sodium) hydroxide in a steam boiler on
tripoli or infusorial earth, which contains a large proportion of
amorphous silica. All solutions of the alkaline silicates have an
alkaline reaction, and are even decomposed by carbonic acid. They
are chiefly used by the dyer, for the same purposes as sodium
aluminate, and also for giving a hardness and polish to stucco and
other cements, and in general to substances which contain lime. A
lump of chalk when immersed in soluble glass, or better still when
moistened with a solution and afterwards washed in water (or
better in hydrofluosilicic acid, in order to bind together the
free alkali and make it insoluble), becomes exceedingly hard,
loses its friability, is rendered cohesive, and cannot be
levigated in water. This transformation is due to the fact that
the hydrate of silica present in the solution acts upon the lime,
forming a stony mass of calcium silicate, whilst the carbonic acid
previously in combination with the lime enters into combination
with the alkali and is washed away by the water.
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