The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[15] The equation given above does not express the actual reaction, for
in the first place silica has the faculty of forming compounds
with bases, and therefore the formula SiNa_{4}O_{4} is not rightly
deduced, if one may so express oneself. And, in the second place,
silica gives several hydrates. In consequence of this, the hydrate
precipitated does not actually contain so high a proportion of
water as Si(OH)_{4}, but always less. The insoluble gelatinous
hydrate which separates out is able (before, but not after, having
been dried) to dissolve in a solution of sodium carbonate. When
dried in air its composition corresponds with the ordinary salts
of carbonic acid--that is, SiH_{2}O_{3}, or SiO(OH)_{2}. If
gradually heated it loses water by degrees, and, in so doing,
gives various degrees of combination with it. The existence of
these degrees of hydration, having the composition
SiH_{2}O_{3}_n_SiO_{2}, or, in general, _n_SiO_{2}_m_H_{2}O, where
_m_ < _n_, must be recognised, because most varied degrees of
combination of silica with bases are known. The hydrate of silica,
when not dried above 30°, has a composition of nearly
H_{4}Si_{3}O_{8} = (H_{2}SiO_{3})_{2}SiO_{2}, but at 60° contains
a greater proportion of silica--that is, it loses still more
water; and at 100° a hydrate of the composition
SiH_{2}O_{3}2SiO_{2}, and at 250° a hydrate having approximately a
composition SiH_{2}O_{3}7SiO_{2} is obtained.
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