The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
These data show the complexity of the molecules of anhydrous
silica. The hydrates of silica easily lose water and give the
hydrates (SiO_{2})_{_n_}(H_{2}O)_{_m_}, where _m_ becomes smaller
and smaller than _n_. In the natural hydrates, this decrement of
water proceeds quite consecutively, and, so to say, imperceptibly,
until _n_ becomes incomparably greater than _m_, and when the
ratio becomes very large, anhydrous silica of the two
modifications 2·6 and 2·2 is obtained. The composition
(SiO_{2})_{10},H_{2}O still corresponds with 2·9 p.c. of water,
and natural hydrates often contain still less water than this.
Thus some opals are known which contain only 1 p.c. of water,
whilst others contain 7 and even 10 p.c. As the artificially
prepared gelatinous hydrate of silica when dried has many of the
properties of native opals, and as this hydrate always loses water
easily and continually, there can be no doubt that the transition
of (SiO_{2})_{_n_}(H_{2}O)_{_m_} into anhydrous silica, both
amorphous and crystalline (in nature, chalcedony), is accomplished
gradually. This can only be the case if the magnitude of _n_ be
considerable, and therefore the molecule of silica in the hydrate
is undoubtedly complex, and hence the anhydrous silica of sp. gr.
2·2 and 2·6 does not contain SiO_{2}, but a complex molecule,
Si_{_n_}O_{2_n_}--that is, the structure of silica is polymeric
and complex, and not simple as represented above by the formula
SiO_{2}.
Neither of the two varieties of anhydrous silica, nor the various
natural gelatinous hydrates, are directly soluble in water. There is,
however, a condition of silica known which is soluble in water, _soluble
silica_, and silica is found in this state in nature. Small quantities of
soluble silica are met with in all waters. Certain mineral springs, and
especially hot springs--of which the best known are the Geysers of
Iceland and those in the North American National Park (Yellowstone
Valley)--contain a considerable amount of silica in solution. Such water,
permeating the objects it meets with--for instance, wood--penetrates into
them and deposits silica inside them, that is, transforms them into a
petrified condition. Siliceous stalactites, and also many (if not all)
forms of silica are formed by such water. The absorption of silica by
plants by means of their roots, and also by the lower organisms having
siliceous bodies, is due also to their nourishing themselves with the
solutions containing silica continually formed in nature. Thus, in
plants, in the straws of the grasses, in hard shave-grass, and especially
in the knots of bamboo and other straw-like plants, a considerable
quantity of silica is deposited, which must previously have been absorbed
by the plants.
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