The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[17] _See_ Chapter I., Note 18. A solution of water-glass mixed with an
excess of hydrochloric acid is poured into the dialyser, and the
outer vessel is filled with water, which is continually renewed.
The water carries off the sodium chloride and hydrochloric acid,
and the hydrosol remains in the dialyser.
Thus in addition to the gelatinous form of the silicic acid, there
exists also a variety of this substance, soluble in water, as is the case
with alumina. Such variation in properties and exactly the same relations
with regard to water characterise an immense series of other substances
having a great significance in nature. The number of such substances is
especially great among organic compounds, and particularly in those
classes of them which compose the principal material of the bodies of
animals and plants. It is sufficient to mention, for instance, the
gelatin which is familiar to all as carpenter's and other glues, and in
the form of size and jelly. The same substance is also known in the
solution which is used to join objects together. In a peculiar insoluble
condition it enters into the composition of hides and bones. These
various forms of gelatin differ in the same way as the different
varieties of silica. The property of forming a jelly is exactly the same
as in silica, and the adhesiveness of the solutions of both substances is
identical; soluble silica adheres like a solution of gelatin. The same
properties are again shown by starch, rosin, and albumin, and by a series
of similar substances. The diaphragms used in dialysis are also
insoluble, gelatinous, forms of colloids. The bodies of animals and
plants consist largely of similar matter, insoluble in water,
corresponding with the gelatinous or insoluble silicon hydrate, or with
glue. The albumin which coagulates when eggs are boiled is a typical form
of the gelatinous condition of such substances in the body. These slight
indications are sufficient in order to show how great is the significance
of those transformations which are so well marked in silica. The facts
discovered by _Graham_ in 1861-1864 comprise the most essential
acquisitions in the general association of these phenomena of nature in
the history of organic forms. The facility of transit from hydrogel to
hydrosol is the first condition of the possibility of the development of
organisms. The blood contains hydrosols, and the hydrogels of the same
substances are contained in the muscles and tissues, and especially on
the surface, of the body. All tissues are formed from the blood, and in
that case the hydrosols are converted into hydrogels.[18] The absence of
crystallisation, the property, apparently under the influence of feeble
agencies, of passing from the soluble condition to the insoluble, to the
gelatinous condition of the hydrogel, constitute the fundamental
properties of all colloids.[19]
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