The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[22] It is, however, easy to imagine, and experience confirms the
supposition, that in a complex siliceous compound containing for
instance sodium and calcium, the whole of the sodium may be
replaced by potassium, and _at the same time_ the whole of the
calcium by magnesium, because then the substitution of potassium
for the sodium will produce a change in the nature of the
substance contrary to that which will occur from the calcium being
replaced by magnesium. That increase in weight, decrease in
density, increase of chemical energy, which accompanies the
exchange of sodium for potassium will, so to speak, be compensated
by the exchange of calcium for magnesium, because both in weight
and in properties the sum of Na + Ca is very near to the sum of K
+ Mg. _Pyroxene_ or _augite_ can be taken as an example; its
composition may be expressed by the formula CaMgSi_{2}O_{6}; that
is, it corresponds with the acid H_{2}SiO_{3}; it is a bisilicate.
In many respects it closely resembles another mineral called
'_spodumene_' (they are both monoclinic). This latter has the
composition Li_{6}Al_{8}Si_{15}O_{45}. On reducing both formulæ to
an equal contents of silica the following distinction will be
observed between them: spodumene
(Li_{2}O)_{6}(Al_{2}O_{3})_{8}30SiO_{2}; augite
(CaO)_{15}(MgO)_{15}30SiO_{2}. That is, the difference between
them consists in the sum of the magnesia and lime (MgO)_{15} +
(CaO)_{15} replacing the sum of the lithium oxide and alumina
(Li_{2}O)_{6} + (Al_{2}O_{3})_{8}; and in the chemical relation
these sums are near to one another, because magnesium and calcium,
both in forms of oxidation and in energy (as bases), in all
respects occupy a position intermediate between lithium and
aluminium, and therefore the sum of the first may be replaced by
the sum of the second.
If we take the composition of spodumene, as it is often
represented to be, Li_{2}O,Al_{2}O_{3},4SiO_{2}, the corresponding
formula of augite will be (CaO)_{2},(MgO)_{2},4SiO_{2}, and also
the amount of oxygen in the sum of Li_{2}OAl_{2}O_{3} will be the
same as in (CaO)_{2}(MgO)_{2}. I may remark, for the sake of
clearness, that lithium belongs to the first, aluminium to the
third group, and calcium and magnesium to the intermediate second
group; lithium, like calcium, belongs to the even series, and
magnesium and aluminium to the uneven.
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