The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
If the compounds of silica are substances like the metallic
alloys, then (1) the chemical union between the oxides of which
they are composed must be a feeble one, as it is in all compounds
formed between analogous substances. In reality such feeble
agencies as water and carbonic acid are able, although slowly, to
act on and destroy the majority of the complex silica compounds in
rocks, as we saw in the preceding chapter; (2) their formation,
like that of alloys, should not be accompanied by a considerable
alteration of volume; and this is actually the case. For example,
felspar has a specific gravity of about 2·6, and therefore, taking
its composition to be K_{2}O,Al_{2}O_{3},6SiO_{2}, we find its
volume, corresponding with this formula, to be 556·8. 2·6 = 214,
the volume of K_{2}O = 35, of Al_{2}O_{3} = 26, and of SiO_{2} =
22·6. Hence the sum of the volumes of the component oxides, 35 +
26 + 6 × 22·6 = 196, which is very nearly equal to that of the
felspar; that is, its formation is attended by a slight expansion,
and not by contraction, as is the case in the majority of other
cases when combinations determined by strong affinities are
accomplished. In the case in question the same phenomenon is
observed as in solutions and alloys--that is, as in cases of
feeble affinities. So also the specific gravity of glass is
directly dependent on the amount of those oxides which enter into
its composition. If in the preceding example we take the sp. gr.
of silica to be, not 2·65, but 2·2, its volume = 27·3, and the sum
of the volumes will be = 224--that is, greater than that of
orthoclase.
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