The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Among the crystalline silicates the following minerals are
known:--_Wollastonite_ (tabular-spar), crystallises in the
monoclinic system; sp. gr. 2·8; it is semi-transparent,
difficultly fusible, decomposed by acids, and has the composition
of a metasilicate, CaOSiO_{2}. But isomorphous mixtures of calcium
and magnesium silicates occur with particular frequency in nature.
The _augites_ (sp. gr. 3·3), diallages, hypersthenes, hornblendes
(sp. gr. 3·1), amphiboles, common asbestos, and many similar
minerals, sometimes forming the essential parts of entire rock
formations, contain various relative proportions of the
bisilicates of calcium and magnesium partially mixed with other
metallic silicates, and generally anhydrous, or only containing a
small amount of water. In the pyroxenes, as a rule, lime
predominates, and in the amphiboles (also of the monoclinic
system) magnesia predominates. Details upon this subject must be
looked for in works upon mineralogy.
The most remarkable complex siliceous compounds are the _felspars_, which
enter into nearly all the primary rocks like porphyry, granite, gneiss,
&c. These felspars always contain, in addition to silica and alumina,
oxides presenting more marked basic properties, such as potash, soda, and
lime. Thus the _orthoclase_ (adularia), or ordinary felspar (monoclinic)
of the granites, contains K_{2}O,Al_{2}O_{3},6SiO_{2}; _albite_ contains
the same substances, only with Na_{2}O instead of K_{2}O (it already
appertains to the triclinic system); _anorthite_ contains lime, and its
composition is CaO,Al_{2}O_{3},2SiO_{2}. On expressing the two last as
containing equal quantities of oxygen, we have:--
Albite Na_{2} Al_{2} Si_{6} O_{16}
Anorthite Ca_{2} Al_{4} Si_{4} O_{16}
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