The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
It is then evident that on the conversion of albite into anorthite,
Na_{2}Si_{2} is replaced by Ca_{2}Al_{2}, and this sum, both in chemical
energy and in the form of oxide, may be considered as corresponding with
the first, because sodium and silicon are extreme elements in chemical
character (from groups I. and IV.), and calcium and aluminium are means
between them (from groups II. and III.), and actually both these felspar
minerals are not only of one (triclinic) system, but form (Tchermak,
Schuster) all possible kinds of definite compounds (isomorphous mixtures)
between themselves, as indicated by their composition and all their
properties. Thus oligoclase, andesine, labradorite, &c. (plagioclases),
are nothing more than mutual combinations of albite and anorthite.
Labradorite consists of albite, in combination with 1 to 2 molecules of
anorthite. The class of _zeolites_ corresponds to the felspars; they are
hydrated compounds of a similar composition to the felspars. Thus
_natrolite_ contains Na_{2}O,Al_{2}O_{3},3SiO_{2},2H_{2}O, and _analcime_
presents the same composition, but contains 4SiO_{2} instead of 3SiO_{2}.
In general, the felspars and zeolites contain RO,Al_{2}O_{3},_n_SiO_{2},
where _n_ varies considerably.[24]
[24] The majority of the siliceous minerals have now been obtained
artificially under various conditions. Thus N. N. Sokoloff showed
that slags very frequently contain peridote. Hautefeuille,
Chroustchoff, Friedel, and Sarasin obtained felspar identical in
all respects with the natural minerals. The details of the methods
here employed must be looked for in special works on mineralogy;
but, as an example, we will describe the method of the preparation
of felspar employed by Friedel and Sarasin (1881). From the fact
that felspar gives up potassium silicate to water even at the
ordinary temperature (Debray's experiments), they concluded that
the felspar in granites had an aqueous origin (and this may be
supposed to be the case from geological data); then, in the first
place, its formation could not be accomplished unless in the
presence of an excess of a solution of potassium silicate. In
order to render this argument clear I may mention, as an example,
that carnallite is decomposed by water into easily soluble
magnesium chloride and potassium chloride, and therefore if it is
of aqueous origin it could not be formed otherwise than from a
solution containing an excess of magnesium chloride, and, in the
second place, from a strongly-heated solution; again, felspar
itself and its fellow-components in granites are anhydrous. On
these facts were based experiments of heating hydrates of silica
with alumina and a solution of potassium silicate in a closed
vessel. The mixture was placed in a sealed platinum tube, which
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