The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The coefficient of cubical expansion of glass is nearly equal to
that of platinum and iron, being approximately 0·000027. The
specific heat of glass is nearly 0·18, and the specific gravity of
common soda glass is nearly 2·5, of Bohemian glass 2·4, and of
bottle glass 2·7. Flint glass is much heavier than common glass,
because it contains the heavier oxide of lead, its specific
gravity being 2·9 to 3·2.
[27] It must be recollected that although acids seem to act only feebly
on the majority of silicates, nevertheless a finely-levigated
powder of siliceous compounds is acted on by strong acids,
especially with the aid of heat, the basic oxides being taken up
and gelatinous silica left behind. In this respect sulphuric acid
heated to 200° with finely-divided siliceous compounds in a closed
tube acts very energetically.
According to the periodic law, the nearest analogues of silicon ought to
be elements of the uneven series, because silicon, like sodium,
magnesium, and aluminium, belongs to the uneven series.[28] Immediately
after silicon follows ekasilicon or _germanium_, Ge = 72, whose
properties were predicted (1871) before Winkler (1886) in Freiberg,
Saxony (Chapter XV. § 5), discovered this element in a peculiar silver
ore called _argyrodite_, Ag_{6}GeS_{5}.[29] Easily reduced from the oxide
by heating with hydrogen and charcoal, and separated from its solutions
by zinc, metallic germanium proved to be greyish white, easily
crystallisable (in octahedra), brittle, fusible (under a coating of fused
borax) at about 900°, and easily oxidisable; the specific gravity =
5·469, the atomic weight = 72·3, and the specific heat = 0·076,[30] as
might be expected for this element according to the periodic law. The
corresponding _germanium dioxide_, GeO_{2}, is a white powder having a
specific gravity of 4·703; water, especially when boiling, dissolves this
dioxide (1 part of GeO_{2} requires for solution 247 parts of water at
20°, 95 parts at 100°). It forms soluble salts with alkalis and is but
sparingly soluble in acids.[31] In a stream of chlorine the metal forms
_germanium chloride_, GeCl_{4}, which boils at 86°, and has a specific
gravity of 1·887 at 18°; water decomposes it, forming the oxide. All
these properties[32] of germanium, showing its analogy to silicon and
tin, form a most beautiful demonstration of the truth of the periodic
law.[33]
[28] Such elements as silicon, tin, and lead were only brought together
under one common group by means of the periodic law, although the
quadrivalency of tin and lead was known much earlier. Generally
silicon was placed among the non-metals, and tin and lead among
the metals.
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