The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
lastly, at the highest temperature, it becomes homogeneous and
quite liquid, which is necessary for the ultimate elimination of
the carbonic anhydride and solid impurities, which latter collect
at the bottom of the crucible. The temperature is then somewhat
lowered, and the glass is taken out on tubes and blown into
objects of various shapes. In the manufacture of window-glass it
is blown into large cylinders, which are then cut at the ends and
across, and afterwards bent back in a furnace into the ordinary
sheets. After being worked up, all glass objects have to be
subjected to a slow cooling (_annealing_) in special furnaces,
otherwise they are very brittle, as is seen in the so-called
'Rupert's drops,' formed by dropping molten glass into water;
although these drops preserve their form, they are so brittle that
they break up into a fine powder if a small piece be knocked off
them. Glass objects have frequently to be polished and chased. In
the manufacture of mirrors and many massive objects the glass is
cast and then ground and polished. Coloured glasses are either
made by directly introducing into the glass itself various oxides,
which give their characteristic tints, or else a thin layer of a
coloured glass is laid on the surface of ordinary glass. Green
glasses are formed by the oxides of chromium and copper, blue by
cobalt oxide, violet by manganese oxide, and red glass by cuprous
oxide and by the so-called purple of Cassius--_i.e._ a compound of
gold and tin--which will be described later. A yellow coloration
is obtained by means of the oxides of iron, silver, or antimony,
and also by means of carbon, especially for the brown tints for
certain kinds of bottle-glass.
From what has been said about glass it will be understood that it
is impossible to give a definite formula for it, because it is a
non-crystalline or amorphous alloy of silicates; but such an alloy
can only be formed within certain limits in the proportions
between the component oxides. With a large proportion of silica
the glass very easily becomes clouded when heated; with a
considerable proportion of alkalis it is easily acted on by
moisture, and becomes cloudy in time on exposure to the air; with
a large proportion of lime it becomes infusible and opaque, owing
to the formation of crystalline compounds in it; in a word, a
certain proportion is practically attained among the component
oxides in order that the glass formed may have suitable
properties. Nevertheless, it may be well to remark that the
composition of common glass approaches to the formula
Na_{2}O,CaO,4SiO_{2}.
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