The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The appearance of lead is well known; its specific gravity is 11·3; the
bluish colour and well-marked metallic lustre of freshly-cut lead quickly
disappear when exposed to the air, because it becomes coated with a
layer--although a very thin layer--of oxide and salts formed by the
moisture and acids in the atmosphere. It melts at 320°, and crystallises
in octahedra on cooling. Its softness is apparent from the flexibility of
lead pipes and sheets, and also from the fact that it may be cut with a
knife, and also that it leaves a grey streak when rubbed on paper. On
account of its being so soft, lead naturally cannot be applied in many
cases where most metals may be used; but on the other hand it is a metal
which is not easily changed by chemical reagents, and as it is capable of
being soldered and drawn into sheets, &c., lead is most valuable for many
technical uses. Lead pipes are used for conveying water[45] and many
other liquids, and sheet lead is used for lining all kinds of vessels
containing liquids--(acids, for instance) which act on other metals. This
particularly refers to sulphuric and hydrochloric acids, because at a low
temperature they do not act on lead, and if they form lead sulphate,
PbSO_{4}, and chloride, PbCl_{2}, these salts being insoluble in water
and in acids, cover the lead and protect it from further corrosion.[46]
All soluble preparations of lead are poisonous. At a white heat lead may
be partially distilled; the vapours oxidise and burn. Lead may also be
easily oxidised at low temperatures. Lead only decomposes water at a
white heat, and does not liberate hydrogen from acids, with the exception
only of very strong hydrochloric acid and then only when boiling.
Sulphuric acid diluted with water does not act on it, or only acts very
feebly at the surface; but strong sulphuric acid, when heated, is
decomposed by it, with the evolution of sulphurous anhydride. The best
solvent for lead is nitric acid, which transforms it into a soluble salt,
Pb(NO_{3})_{2}.
[45] Freshly laid new lead pipes contaminate the water with a certain
amount of lead salts, arising from the presence of oxygen,
carbonic acid, &c., in the water. But the lead pipes under the
action of running water soon become coated with a film of
salts--lead sulphate, carbonate, chloride, &c.--which are
insoluble in water, and the water pipes then become harmless.
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