The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[46] Lead is used in the arts, and owing to its considerable density,
it is cast, mixed with small quantities of other metals, into
shot. A considerable amount is employed (together with mercury) in
extracting gold and silver from poor ores, and in the manufacture
of chemical reagents, and especially of lead chromate. _Lead
chromate_, PbCrO_{4}, is distinguished for its brilliant yellow
colour, owing to which it is employed in considerable quantities
as a dye, mainly for dyeing cotton tissues yellow. It is formed on
the tissue itself, by causing a soluble salt of lead to react on
potassium chromate. Lead chromate is met with in nature as 'red
lead ore.' It is insoluble in water and acetic acid, hut it
dissolves in aqueous potash. The so-called pewter vessels often
consist of an alloy of 5 parts of tin and 1 part of lead, and
solder is composed of 1 to 2 parts of tin with 1/2 part of lead.
Amongst the alloys of lead and tin, Rudberg states that the alloy
PbSn_{3} stands out from the rest, since, according to his
observations, the temperature of solidification of the alloy is
187°.
Although acids thus have directly but little effect on lead, and this is
one of its most important practical properties, _yet when air has free
access, lead (like copper) very easily reacts with many acids_, even with
those which are comparatively feeble. The action of acetic acid on lead
is particularly striking and often applied in practice. If lead be
plunged into acetic acid it does not change at all and does not pass into
solution, but if part of the lead be immersed in the acid, and the other
part remain in contact with the air, or if lead be merely covered with a
thin layer of acetic acid in such a way that the air is practically in
contact with the metal, then it unites with the oxygen of the air to form
oxide, which combines with the acetic acid and forms lead acetate,
soluble in water. The formation of lead oxide is especially marked from
the fact that with a sufficient quantity of air not only is the normal
lead acetate formed but also the basic salts.[47]
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