The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[48] Few compounds are known of the lower type PbX, and still fewer of
the intermediate type PbX_{3}. To the first type belongs the
so-called lead suboxide, Pb_{2}O, obtained by the ignition of lead
oxalate, C_{2}PbO_{4}, without access of air. It is a black
powder, which easily breaks up under the action of acids, and even
by the simple action of heat, into metallic lead and lead oxide.
This is the character of all suboxides. They cannot be regarded as
independent salt-forming oxides, neither can those forms of
oxidation of lead which contain more oxygen than the oxide of
lead, PbO, and less than the dioxide, PbO_{2}. As we shall see, at
least two such compounds are formed. Thus, for example, an oxide
having the composition Pb_{2}O_{3} is known, but it is decomposed
by the action of acids into lead oxide, which passes into
solution, and lead dioxide, which remains behind. Such is red
lead. (See further on.)
[49] In the boiling of drying oils, the lead oxide partially passes
into solution, forming a saponified compound capable of attracting
oxygen and solidifying into a tar-like mass, which forms the oil
paint. Perhaps, however, glycerine partially acts in the process.
Ossovetsky by saturating drying oil with the salts of certain
metals obtained oil colours of great durability.
A mixture of very finely-divided litharge with glycerine (50 parts
of litharge to 5 c.c. of anhydrous glycerine) forms a very quick
(two minutes) setting cement, which is insoluble in water and
oils, and is very useful in setting up chemical apparatus. The
hardening is based on the reaction of the lead oxide with
glycerine (Moraffsky).
Lead oxide forms but few soluble salts--for instance, the nitrate and the
acetate. The majority of its salts (sulphate, PbSO_{4}; carbonate,
PbCO_{3}; iodide, PbI_{2}, &c.) are insoluble in water. These salts are
colourless or light yellow if the acid be colourless. In lead oxide _the
faculty of forming basic salts_, PbX_{2}_n_PbO or PbX_{2}_n_PbH_{2}O_{2},
is strongly developed. A similar property was observed in magnesium and
also in the salts of mercury, but lead oxide forms basic salts with still
greater facility, although double salts are in this case more rarely
formed.[50]
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