The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
When oxidising in the presence of air,[48] when heated or in the
presence of an acid at the ordinary temperature, lead forms compounds of
the type PbX_{2}. _Lead oxide_, PbO, known in industry as _litharge_,
silberglätte (this name is due to the fact that silver is extracted from
the lead ores of this kind) and massicot. If the lead is oxidised in air
at a high temperature, the oxide which is formed fuses, and on cooling is
easily obtained in fused masses which split up into scales of a yellowish
colour, having a specific gravity of 9·3; in this form it bears the name
of litharge. Litharge is principally used for making lead salts, for the
extraction of metallic lead, and also for the preparation of drying
oils--for instance, from linseed oil.[49] When oxidised carefully and
slightly heated, lead forms a powdery (not fused) oxide known under the
name of _massicot_. It is best prepared in the laboratory by heating lead
nitrate, or lead hydroxide. It has a yellow colour, and differs from
litharge in the greater difficulty with which it forms lead salts with
acids. Thus, for instance, when massicot is moistened with water it does
not attract the carbonic acid of the air so easily as litharge does. It
may, however, be imagined that the cause of the difference depends only
on the formation of dioxide on the surface of the lead oxide, on which
the acids do not act. In any case lead oxide is comparatively easily
soluble in nitric and acetic acids. It is but slightly soluble in water,
but communicates an alkaline reaction to it, since it forms the
hydroxide. This hydroxide is obtained in the shape of a white precipitate
by the action of a small quantity of an alkali hydroxide on a solution of
a lead salt. An excess of alkali dissolves the hydroxide separated, which
fact demonstrates the comparatively indistinct basic properties of lead
oxide. The normal lead hydroxide, which should have the composition
Pb(OH)_{2}, is unknown in a separate state, but it is known in
combination with lead oxide as Pb(OH)_{2},2PbO or Pb_{3}O_{2}(OH)_{2}.
The latter is obtained in the form of brilliant, white, octahedral
crystals when basic lead acetate is mixed with ammonia and gently heated.
The basic qualities of this hydroxide are shown distinctly by its
absorbing the carbonic anhydride of the air. When an alkaline solution of
the hydroxide is boiled, it deposits lead oxide in the form of a
crystalline powder.
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