The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[38] The feebleness of the acid properties of arsenious anhydride is
seen in the fact that if it be dissolved in ammonia water, and
then a still stronger solution of ammonia be added, prismatic
crystals separate having the composition of ammonium metarsenite,
NH_{4}AsO_{3}. This ammonium salt deliquesces in air, and loses
all its ammonia. The magnesium salt is tri-metallic,
Mg_{3}(AsO_{3})_{2}; it is insoluble in water, and is formed by
mixing an ammoniacal solution of arsenious anhydride with an
ammoniacal solution of a magnesium salt. It is insoluble even in
ammonia, although it dissolves in an excess of acids. Magnesium
hydroxide gives the same salt with arsenious solutions, and hence
magnesia is one of the best antidotes for arsenic poisoning. _The
arsenites of copper_ are much used in the manufacture of colours,
more especially of pigments. They are distinguished by their
insolubility in water and by their remarkably vivid green colour,
but at the same time by their poisonous character. Not only do
such pigments applied to wall papers or other materials easily
dust off from them, but they give exhalations containing AsH_{3}.
The cupric salts, CuX_{2}, when mixed with an alkaline solution of
arsenious acid, give a green precipitate of a copper salt called
_Scheele's green_. Its composition is probably CuHAsO_{3}. Ammonia
dissolves it, and gives a colourless solution, containing cuprous
arsenate--that is, the cupric compound is reduced and the arsenic
subjected to a further oxidation. The so-called _Schweinfurt
green_ was still more used, especially in former times; it is an
insoluble green cupric salt, which resembles the preceding in many
respects, but has a different tint. It is prepared by mixing
boiling solutions of arsenious acid and cupric acetate. Arsenious
acid forms an insoluble compound with ferric hydroxide, resembling
the phosphate; and this is the reason why freshly precipitated
oxide of iron is employed as an _antidote for arsenic_. The
freshly precipitated oxide of iron, taken immediately after
poisoning by arsenic, converts the arsenious acid into an
insoluble state, by forming a compound on which the acids of the
stomach have no action, so that the poisoning cannot proceed. It
is remarkable that the inhabitants of certain mountainous
countries accustom themselves to taking arsenic, as a means which,
according to their experience, helps to overcome the fatigue of
mountain ascents. Arsenious anhydride and certain of its salts are
also used in medicine, naturally only in small quantities. When
taken internally arsenic passes into the blood, and is mainly
excreted by the urine.
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