The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Bismuth forms compounds of two types, BiX_{3} and BiX_{5},[43] which
entirely recall the two types we have already established for the
compounds of lead. Just as in the case of lead, the type PbX_{2}, is
basic, stable, easily formed, and passes with difficulty into the higher
and lower types, which are unstable, so also in the case of bismuth the
type of combination BiX_{3} is the usual basic form. The higher type of
combination, BiX_{5},[44] in fact behaves toward this stable type,
BiX_{3}, in exactly the same manner as lead dioxide does to the monoxide;
and bismuthic acid is obtained by the action of chlorine on bismuth oxide
suspended in water, in exactly the same way as lead dioxide is obtained
from lead oxide. It is an oxidising agent like lead dioxide, and even the
acid character in bismuthic acid is only slightly more developed than in
lead dioxide. Here, as in the case of lead (minium), intermediate
compounds are easily formed in which the bismuth of the lower oxide plays
the part of a base combined with the acid which is formed by the higher
form of the oxidation of bismuth.
[43] Metallic bismuth is very easily obtained when the compounds of the
oxide are reduced by powerful reducing agents, but when less
powerful reducing agents--for example, stannous oxide--are taken,
bismuth suboxide is formed as a black crystalline powder. It is a
compound of the type BiX_{2}, its composition being BiO; it is
decomposed by acids into the metal and oxide, which passes into
solution.
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