The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
dissolved in an excess of hydrochloric acid, and the solution
diluted with a considerable amount of water, then this same powder
of algaroth is precipitated. The composition varies with the
relative amount of water; namely, between the limits SbOCl and
Sb_{4}O_{5}Cl_{2}. The latter compound is, as it were, a basic
salt of the former, because its composition = 2(SbOCl)Sb_{2}O_{3}.
With bromine and iodine, antimony forms compounds similar to those
with chlorine. Antimonious bromide, SbBr_{3}, crystallises in
colourless prisms, melts at 94°, and boils at 270°; antimonious
iodide, SbI_{3}, forms red crystals of sp. gr. 5·0; antimony
trifluoride, SbF_{3} separates from a solution of antimonious
oxide in hydrofluoric acid, and SbF_{5} is formed by a similar
treatment of antimonic acid. The latter gives easily-soluble
double salts with the fluorides of the metals of the alkalis.
De Haën (1887) obtained very stable double soluble salts,
SbF_{3},KCl (100 parts of water dissolve 57 parts of salt),
SbF_{3},K_{2}SO_{4}, &c., which he proposed to make use of in the
arts as very easily crystallisable and soluble salts of antimony.
Engel, by passing hydrochloric acid gas into a saturated solution
of antimonious chloride at 0°, obtained a compound
HCl,2SbCl_{3},2H_{2}O, and with the pentachloride a compound
SbCl_{5},5HCl,10H_{2}O. Bismuth trichloride, BiCl_{3}, gives a
similar compound.
Saunders (1892) obtained 5RbCl,3SbCl_{3} and RbCl,SbCl_{3}. Ditte
and Metzner (1892) showed that Sb and Bi dissolve in hydrochloric
acid only owing to the participation of the oxygen of the air or
of that dissolved in the acid.
The heaviest analogue of nitrogen and phosphorus is _bismuth_, Bi = 208.
Here, as in the other groups, the basic, metallic, properties increase
with the atomic weight. Bismuth does not give any hydrogen compound and
the highest oxide, Bi_{2}O_{5}, is a very feeble acid oxide. Bismuthous
oxide, Bi_{2}O_{3}, is a base, and bismuth itself a perfect metal. To
explain the other properties of bismuth it must further be remarked that
in the eleventh series it follows mercury, thallium and lead, whose
atomic weights are near to that of bismuth, and that therefore it
resembles them and more especially its nearest neighbour, lead. Although
PbO and PbO_{2}, represent types different from Bi_{2}O_{3} and
Bi_{2}O_{5}, they resemble them in many respects, even in their external
appearance, moreover the lower oxides both of Pb and Bi are basic and the
higher acid, which easily evolve oxygen. But judging by the formula,
Bi_{2}O_{3} is a more feeble base than PbO. They both easily give basic
salts.
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