The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
as charcoal about 6, for nickel and cobalt less than 7, for iridium and
platinum about 9. The remaining elements having atomic weights and
properties intermediate between those elements mentioned above have also
intermediate atomic volumes. Therefore _the specific gravities and
specific volumes of solids and liquids stand in periodic dependence on
the atomic weights_, as is seen in Table III., where both _A_ (the atomic
weight) and _d_ (the specific gravity), and _A_/_d_ (specific volumes of
the atoms) are given (column 18).
[19 bis] Probably, besides thermo-chemical data (Note 19), the
refractive index, cohesion, ductility, and similar properties of
corresponding compounds or of the elements themselves will be
found to exhibit a dependence of the magnitude of the atomic
weight upon the periodic law.
[20] Having occupied myself since the fifties (my dissertation for the
degree of M.A. concerned the specific volumes, and is printed in
part in the _Russian Mining Journal_ for 1856) with the problems
concerning the relations between the specific gravities and
volumes, and the chemical compositions of substances, I am
inclined to think that the direct investigation of specific
gravities gives essentially the same results as the investigation
of specific volumes, only that the latter are more graphic. Table
III. of the periodic properties of the elements clearly
illustrates this. Thus, for those members whose volume is the
greatest among the contiguous elements, the specific gravity is
least--that is, the periodic variation of both properties is
equally evident. In passing, for instance, from silver to iodine
we have a successive decrease of specific gravity and successive
increase of specific volume. The periodic alternation of the rise
and fall of the specific gravity and specific volume of the free
elements was communicated by me in August 1869 to the Moscow
Meeting of Russian Naturalists. In the following year (1870) L.
Meyer's paper appeared, which also dealt with the specific volume
of the elements.
[21] In my opinion the mean volume of the atoms of compounds deserves
more attention than has yet been paid to it. I may point out, for
instance, that for feebly energetic oxides the mean volume of the
atom is generally nearly 7; for example, the oxides SiO_{2},
Sc_{2}O_{3}, TiO_{2}, V_{2}O_{5}, as well as ZnO, Ga_{2}O_{3},
GeO_{2}, ZrO_{2}, In_{2}O_{3}, SnO_{2}, Sb_{2}O_{5}, &c., whilst
the mean volume of the atom of the alkali and acid oxides is
greater than 7. Thus we find in the magnitudes of the mean volumes
of the atom in oxides and salts both a periodic variation and a
connection with their energy of essentially the same character as
occurs in the case of the free elements.
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