The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Thus we find that in the large periods beginning with lithium, sodium,
potassium, rubidium, cæsium, and ending with fluorine, chlorine, bromine,
iodine, the extreme members (energetic elements) have a small density and
large volume, whilst the intermediate substances gradually increase in
density and decrease in volume--that is, as the atomic weight increases
the density rises and falls, again rises and falls, and so on.
Furthermore, the energy decreases as the density rises, and the greatest
density is proper to the atomically heaviest and least energetic
elements; for example, Os, Ir, Pt, Au, U.
In order to explain the relation between the volumes of the elements and
of their compounds, the densities (column S) and volumes (column M/_s_)
of some of the higher saline oxides arranged in the same order as in the
case of the elements are given on p. 36. For convenience of comparison
the volumes of the oxides are all calculated per two atoms of an element
combined with oxygen. For example, the density of Al_{2}O_{3} = 4·0,
weight Al_{2}O_{3} = 102, volume Al_{2}O_{3} = 25·5. Whence, knowing the
volume of aluminium to be 11, it is at once seen that in the formation of
aluminium oxide, 22 volumes of it give 25·5 volumes of oxide. A distinct
periodicity may also be observed with respect to the specific gravities
and volumes of the higher saline oxides. Thus in each period, beginning
with the alkali metals, the specific gravity of the oxides first rises,
reaches a maximum, and then falls on passing to the acid oxides, and
again becomes a minimum about the halogens. But it is especially
important to call attention to the fact that the volume of the alkali
oxides is less than that of the metal contained in them, which is also
expressed in the last column, giving this difference for each atom of
oxygen.[22] Thus 2 atoms of sodium, or 46 volumes, give 24 volumes of
Na_{2}O, and about 37 volumes of 2NaHO--that is, the oxygen and hydrogen
in distributing themselves in the medium of sodium have not only not
increased the distance between its atoms, but have brought them nearer
together, have drawn them together by the force of their great affinity,
by reason, it may be presumed, of the small mutual attraction of the
atoms of sodium. Such metals as aluminium and zinc, in combining with
oxygen and forming oxides of feeble salt-forming capacity, hardly vary in
volume, but the common metals and non-metals, and especially those
forming acid oxides, always give an increased volume when oxidised--that
is, the atoms are set further apart in order to make room for the oxygen.
The oxygen in them does not compress the molecule as in the alkalis; it
is therefore comparatively easily disengaged.
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