The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[22] The volume of oxygen (judging by the table on p. 36) is evidently
a variable quantity, forming a distinctly periodic function of the
atomic weight and type of the oxide, and therefore the efforts
which were formerly made to find the volume of the atom of oxygen
in the volumes of its compounds may be considered to be futile.
But since a distinct contraction takes place in the formation of
oxides, and the volume of an oxide is frequently less than the
volume in the free state of the element contained in it, it might
be surmised that the volume of oxygen in a free state is about 15,
and therefore the specific gravity of solid oxygen in a free state
would be about O·9.
S M/_s_ Volume of Oxygen
H_{2}O 1·0 18 ?- 22
Li_{2}O 2·0 15 - 9
Be_{2}O_{2} 3·06 16 + 2·6
B_{2}O_{3} 1·8 39 + 10·0
C_{2}O_{4} 1·6 55 + 10·6
N_{2}O_{5} 1·64 66 ?+ 4
Na_{2}O 2·6 24 - 22
Mg_{2}O_{2} 3·5 23 - 4·5
Al_{2}O_{3} 4·0 26 + 1·3
Si_{2}O_{4} 2·65 45 + 5·2
P_{2}O_{5} 2·39 59 + 6·2
S_{2}O_{6} 1·96 82 + 8·7
Cl_{2}O_{7} ?1·92 95 + 6
K_{2}O 2·7 35 - 35
Ca_{2}O_{2} 3·25 34 - 8
Sc_{2}O_{3} 3·86 35 ? 0
Ti_{2}O_{4} 4·2 38 + 3
V_{2}O_{5} 3·49 52 + 6·7
Cr_{2}O_{6} 2·74 73 + 9·5
Cu_{2}O 5·9 24 + 9·6
Zn_{2}O_{2} 5·7 23 + 4·8
Ga_{2}O_{3} ?5·1 36 + 4
Ge_{2}O_{4} 4·7 44 + 4·5
As_{2}O_{5} 4·1 56 + 6·0
Sr_{2}O_{2} 4·7 44 - 13
Y_{2}O_{3} 5·0 45 ?- 2
Zr_{2}O_{4} 5·5 44 0
Nb_{2}O_{5} 4·7 57 + 6
MoO_{6} 4·4 65 + 6·8
Ag_{2}O 7·5 31 + 11
Cd_{2}O_{3} 8·0 32 + 3
In_{2}O_{3} 7·18 38 + 2·7
Sn_{2}O_{4} 7·O 43 + 2·7
Sb_{2}O_{5} 6·5 49 + 2·6
TeO_{6} 5·1 68 + 4·7
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