The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The last line shows the change of specific gravity for 1° in
ten-thousandth parts for temperatures near 15°. More accurate
determinations of Cheltzoff, personally communicated by him, led
him to conclude that solutions of zinc chloride follow the same
laws as the solutions of sulphuric acid, which will be considered
in Chapter XX.: (1) from H_{2}O to ZnCl_{2},120H_{2}O _s_ = S_{0} +
92·85_p_ + 0·1748_p_^2; (2) from thence to ZnCl_{2},40H_{2}O _s_ =
S_{0} + 93·96_p_ - 0·0126_p_^2; (3) thence to ZnCl_{2},25H_{2}O _s_
= 11481·5 + 96·45(_p_ - 15·89) + 0·4567(_p_ - 15·89)^2; (4) thence
to ZnCl_{2},10H_{2}O _s_ = 12212·1 + 104·82(_p_ - 23·21) +
0·7992(_p_ - 23·21)^2; (5) thence to _p_ = 65 p.c. _s_ = 14606·3 +
140·96(_p_ - 43·05) + 1·4905(_p_ - 43·05)^2, where _s_ is the
specific gravity of the solution at 15°, containing _p_ p.c. of
ZnCl_{2} by weight, taking water at 4° = 10000, and where S_{0} =
9991·6 (specific gravity of water at 15°). The compound of zinc
chloride with hydrochloric acid has been mentioned in Vol. I.
Chapter X.
Zinc chloride has a great affinity for water; it is not only
soluble in it, but in alcohol, and on being dissolved in water
becomes considerably heated, like magnesium and calcium chlorides.
Zinc chloride is capable of taking up water, not only in a free
state, but also in chemical combination with many substances. Thus,
for instance, it is used in organic researches for removing the
elements of water from many of the organic compounds.
Public-domain text, read in full here on John Shaqi.
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