The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
strong alkali is mixed with a large mass of water, nearly all the
oxide of zinc is precipitated; and, therefore, in weak solutions, a
large quantity of the alkali is required to effect solution, which
points to the decomposition of the zinc-alkali compounds by water.
If strong alcohol be added to a solution of zinc oxide in sodium
hydroxide, the crystallo-hydrate, 2Zn(OH)(ONa),7H_{2}O, separates.
[4] _Zinc chloride_, ZnCl_{2}, is generally employed in the arts in the
form of a solution obtained by dissolving zinc in hydrochloric
acid. This solution is used for soldering metals, impregnating
wood, &c. The reason why it is thus employed may be understood from
its properties. When evaporated it first parts with its water of
crystallisation; on being further heated, however, it loses all
traces of water, and forms an oily mass of anhydrous salt which
solidifies on cooling. This substance melts at 250°, commences to
volatilise at about 400°, and boils at 730°. The soldering of
metals--that is, the introduction of an easily fusible metal
between two contiguous metallic objects--is hindered by any film of
oxide upon them; and, as heated metals easily oxidise, they are
naturally difficult to solder. Zinc chloride is used to prevent the
oxidation. It fuses on being heated, and, covering the metal with
an oily coating, prevents contact with the air; but even if any
oxide has formed, the free hydrochloric acid generally existing in
the zinc chloride solution dissolves it, and in this way the
metallic surface of the metals to be soldered is preserved fit for
the adhesion of the liquid solder, which, on cooling, binds the
objects together. Much zinc chloride is used also for steeping wood
(telegraph-posts and railway-sleepers) in order to preserve it from
decaying quickly; this preservative action is in all probability
mainly due to the poisonous character of zinc salts (corrosive
sublimate is still more poisonous, and a still better agent to
preserve wood from decay), since decay is due to the action of
lower organisms.
The specific gravity of solutions containing _p_ per cent. of zinc
chloride, ZnCl_{2}, is as follows:
_p_ = 10 20 30 40 50
15°/4° = 1·093 1·184 1·293 1·411 1·554
_ds/dt_ = -3 -5 -7 -8 -9
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