The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[8] This zinc, although homogeneous, still contains certain impurities,
to remove which it is necessary to prepare some salt of zinc in a
pure state and transform it into carbonate, which latter is then
distilled with charcoal; and, as thin sheets of zinc can only be
obtained from very pure metal, they are frequently made use of in
cases where pure zinc is required. In order to remove the arsenic
from zinc, it was proposed to melt it and mix it with anhydrous
magnesium chloride, by which means vapours of zinc chloride and
arsenic chloride are formed. Perfectly pure zinc is made (V. Meyer
and others) by decomposing, by means of the galvanic current, a
solution of zinc sulphate to which an excess of ammonia has been
added. The zinc used for Marsh's arsenic test (Chapter XIX.) is
purified from As by fusing it with KNO_{3} and then with ZnCl_{2}.
Metallic zinc has a bluish-white colour; its lustre, compared with many
other metals, is insignificant. When cast it exhibits a crystalline
structure. Its specific gravity is about 7--that is, varies from 6·8 to
7·2, according to the degree of compression (by forging, rolling, &c.) to
which it has been subjected. It is very ductile, considering its
hardness. For this reason it chokes up files when being worked. Its
malleability is considerable when pure, but in the ordinary impure
condition in which it is sold, it is impossible to roll it at the
ordinary temperature, as it easily breaks. At a temperature of 100°,
however, it easily undergoes such operations, and can then be drawn into
wire or rolled into sheets. If heated further it again becomes brittle,
and at 200° may be even crushed into powder, so completely does it lose
its molecular cohesion. It melts at 418°, and distils at 930°.
Zinc does not undergo any change in the atmosphere. Even in very damp air
it only becomes slowly coated with a very thin white coating of oxide.
For this reason it is available for all objects which are only in contact
with air. Therefore sheet zinc may be used for roofing and many other
purposes.[9] This great unchangeability of zinc in the air shows its
slight energy with regard to oxygen compared with the metals already
mentioned, which are capable of reducing zinc from solutions. But zinc
plays this part with regard to the remaining metals--for example, it
reduces salts of lead, copper, mercury, &c. Although zinc is an almost
unoxidisable metal at the ordinary temperature, it burns in the air on
being heated, particularly when in the form of shavings or in the
condition of vapour. At the ordinary temperature zinc does not decompose
water--at any rate, if the metal be in a dense mass. But even at a
temperature of 100° zinc begins little by little to decompose water; it
easily displaces the hydrogen of acids at the ordinary temperature, and
of alkalis on being heated.
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