The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[9] Cornices and other architectural ornaments, remarkable for their
lightness and beauty, are stamped out of sheet zinc. Zinc-roofing
does not require painting, but it melts during a conflagration, and
even burns at a strong heat. Many iron vessels, &c., are covered
with zinc ('galvanised') in order to prevent them from rusting.
In this respect the action of zinc varies a great deal with the degree
of its purity. Weak sulphuric acid (corresponding with the composition
H_{2}SO_{4},8H_{2}O) at the ordinary temperature does not act at all on
chemically pure zinc, and even a stronger solution acts very slowly. If
the temperature be raised, and particularly if the zinc be previously
slightly heated, so as to cover the surface with a film of oxide,
chemically pure zinc acts on sulphuric acid. Thus, for example, one cubic
centimetre of zinc in sulphuric acid having a composition
H_{2}SO_{4},6H_{2}O at the ordinary temperature in two hours only
dissolves to the extent of 0·018 gram, and at a temperature of 100° about
3·5 grams. If we compare this slow action with that rapid evolution of
hydrogen which occurs in the case of commercial zinc, we see that the
influence of those impurities in the zinc is very great. Every particle
of charcoal or iron introduced into the mass of the zinc, and likewise
the connection of the zinc with a piece of another electro-negative
metal, assists such a dissolution. The slowness of the action of
sulphuric acid on pure zinc (and likewise on amalgamated zinc) may also
be explained by the fact that a layer of hydrogen[10] collects on the
surface of the metal, preventing contact between the acid and the
metal.[10 bis]
[10] Veeren (1891) proved this by simple experiments, finding that in
vacuo the solution proceeds far more rapidly for both pure and
commercial zinc, and still more rapidly in the presence of
oxidising agents (which absorb the hydrogen) like CrO_{3} and
H_{2}O_{2}.
[10 bis] The addition of cupric sulphate, or, better still, a few drops
of platinic chloride (the metals become reduced), to the sulphuric
acid greatly accelerates the evolution of the hydrogen, because in
this case, as with commercial zinc, galvanic couples are formed
locally by the copper or platinum and the zinc, under the
influence of which the zinc rapidly dissolves. The action of acids
on metallic zinc of various degrees of purity has been the subject
of many investigations, particularly important with reference to
the application of zinc in galvanic batteries, whilst some
investigations have direct significance for chemical mechanics,
although from many points of view the matter is not clear. I
consider it useful to mention certain of these investigations.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account