The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Mercury, as everybody knows, is a liquid metal at the ordinary
temperature. In its lustre and whiteness it resembles silver.[15] At -39°
mercury is transformed into a malleable crystalline metal; at 0° its
specific gravity is 13·596, and in the solid state at -40° it is
14·39.[16] Mercury does not change in the air--that is to say, it does
not oxidise at the ordinary temperature--but at a temperature approaching
the boiling-point, as was stated in the Introduction, it oxidises,
forming mercuric oxide. Both metallic mercury and its compounds in
general produce salivation, trembling of the hands, and other unhealthy
symptoms which are found in the workmen exposed to the influence of
mercurial vapours or the dust of its compounds.
[15] Mercury may sometimes be obtained in a perfectly pure state from
works (in iron bottles holding about 35 kilos), but after being
used in laboratories (for baths, calibration, &c.) it contains
impurities. It may be purified mechanically in the following way:
a paper filter with a fine hole (pricked with a needle) is placed
in a glass funnel and mercury is poured into it, which slowly
trickles through the hole, leaving the impurities upon the filter.
Sometimes it is squeezed through chamois leather or through a
block of wood (as in the well-known experiment with the air-pump).
It may be purified from many metals by contact with dilute nitric
acid, if small drops of mercury are allowed to pass through a long
column of it (from the fine end of a funnel); or by shaking it up
with sulphuric acid in air. Mercury may be purified by the action
of an electric current, if it be covered with a solution of
HgNO_{3}. But the complete purification of mercury for barometers
and thermometers can only be attained by distillation, best in a
vacuum (the vapour-tension of mercury is given in Chapter II.,
Note 27). For this purpose Weinhold's apparatus is most often
used. The principle of this apparatus is very ingenious, the
distillation being effected in a Torricellian vacuum continuously
supplied with fresh mercury, whilst the condensed mercury is
continuously removed. This process of distillation requires very
little attention, and gives about one kilo of pure mercury per
hour.
[16] If the volume of _liquid_ mercury at 0° be taken as 1000000, then,
according to the determinations of Regnault (recalculated by me in
1875), at _t_ it will be 1000000 + 180·1_t_ + 0·02_t_^2.
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