The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Mercury is found _in nature_ almost exclusively in combination with
sulphur (like zinc and cadmium, but is still rarer than them) in the form
known as cinnabar, HgS (Chapter XX., Note 29). It is far more rarely met
with in the native or metallic condition, and this in all probability has
been derived from cinnabar. Mercury ore is found only in a few
places--namely, in Spain (in Almaden), in Idria, Japan, Peru, and
California. About the year 1880 Minenkoff discovered a rich bed of
cinnabar in the Bahmout district (near the station of Nikitovka), in the
Government of Ekaterinoslav, so that now Russia even exports mercury to
other countries. Cinnabar is now being worked in Daghestan in the
Caucasus. Mercury ores are easily reduced to metallic mercury, because
the combination between the metal and the sulphur is one of but little
stability. Oxygen, iron, lime, and many other substances, when heated,
easily destroy the combination. If iron is heated with cinnabar, iron
sulphide is formed; if cinnabar is heated with lime, mercury and calcium
sulphide and sulphate are formed, 4HgS + 4CaO = 4Hg + 3CaS + CaSO_{4}. On
being heated in the air, or roasted, the sulphur burns, oxidises, forming
sulphurous anhydride, and vapours of metallic mercury are formed. Mercury
is more easily distilled than all other metals, its boiling point being
about 351°, and therefore its separation from natural admixtures,
decomposed by one of the above-mentioned methods, is effected at the
expense of a comparatively small amount of heat. The mixture of mercury
vapour, air, and products of combustion obtained is cooled in tubes (by
water or air), and the mercury condenses as liquid metal.[14]
[14] During the condensation of the vapours of mercury in works, a part
forms a black mass of finely-divided particles, which gives
metallic mercury when worked up in centrifugal machines, or on
pressure, or on re-distillation. In mercury we observe a tendency
to easily split up into the finest drops, which are difficult to
unite into a dense mass. It is sufficient to shake up mercury with
nitric and sulphuric acids in order to produce such a mercury
_powder_. The mercury separated (for instance, reduced by
substances like sulphurous anhydride) from solutions, forms such a
powder. According to the experiments of Nernst, this disintegrated
mercury when entering into reactions develops more heat than the
dense liquid metal--that is to say, the work of disintegration
reappears in the form of heat. This example is instructive in
considering thermochemical deductions.
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