The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[23 bis] As feebly energetic bases (for instance, the oxides MgO, ZnO,
PbO, CuO, Al_{2}O_{3}, Bi_{2}O_{3}, &c.), mercuric oxide (_see_
Notes 20, 21) and mercurous oxide easily give basic salts, which
are usually directly formed by the action of water on the normal
salt, according to the general equation (for mercuric compounds,
RX_{2}):
_n_RX_{2} + _m_H_{2}O = 2_m_HX + (_n_-_m_)RX_{2}_m_RO
neutral salt water acid basic salt
or else are produced directly from the normal salt and the oxide
or its hydroxide. Thus mercurous nitrate, when treated with water,
forms basic salts of the composition 6(HgNO_{3}),Hg_{2}O,H_{2}O,
2(HgNO_{3}),Hg_{2}O,H_{2}O, and 3(HgNO_{3}),Hg_{2}O,H_{2}O, the
first two of which crystallise well. Naturally it is possible
either to refer similar salts to the type of hydrates--for
instance, the second salt to the hydrate N_{2}O_{5},4H_{2}O--or to
view it as a compound, HgNO_{3},HgHO, but our present knowledge of
basic salts is not sufficiently complete to admit of
generalisations. However, it is already possible to view the
subject in the following aspects: (1) basic salts are principally
formed from feeble bases; (2) certain metals (mentioned above)
form them with particular ease, so that one of the causes of the
formation of many basic salts must depend on the property of the
metal itself; (3) those bases which readily form basic salts as a
rule also readily form double salts; (4) in the formation of basic
salts, as also everywhere in chemistry, where sufficient facts
have accumulated, we clearly see the conditions of equally
balanced heterogeneous systems, such as we saw, for instance, in
the formation of double salts, crystallo-hydrates, &c.
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