The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The mercuric salts often form double salts (confirming the third
thesis), and mercuric chloride easily combines with ammonia,
forming Hg(NH_{4})_{2}Cl_{4}, or in general HgCl_{2}_n_MCl. If a
mixture of mercurous and potassium sulphates be dissolved in
dilute sulphuric acid, the solution easily yields large colourless
crystals of a double salt of the composition
K_{2}SO_{4},3HgSO_{4},2H_{2}O. Boullay obtained crystalline
compounds of mercuric chloride with hydrochloric acid, and
mercuric iodide with hydriodic acid; and Thomsen describes the
compound HgBr_{2},HBr,4H_{2}O as a well-crystallised salt, melting
at 13°, and having, in a molten state, a specific gravity 3·17 and
a high index of refraction. Moreover, the capacity of salts for
forming basic compounds has been considerably cleared up since the
investigation (by Würtz, Lorenz, and others) of glycol,
C_{2}H_{4}(OH)_{2} (and of polyatomic alcohols resembling it),
because the ethers C_{2}H_{4}X_{2}, corresponding with it, are
capable of forming compounds containing
C_{2}H_{4}X_{2}_n_C_{2}H_{4}O.
On the other hand, there is reason to think that the property of
forming basic salts is connected with the polymerisation of bases,
especially colloidal ones (_see_ the chapter on Silica, Lead
Salts, and Tungstic Acid).
[24] Mercuric iodide, HgI_{2}, is obtained first as a yellow, and then
as a red, precipitate on mixing solutions of mercuric salts and
potassium iodide, and is soluble in an excess of the latter (in
consequence of the formation of the double salt, HgKI_{3}); of
ammonium chloride (for a similar reason), &c. It crystallises at
the ordinary temperature in square prisms of a red colour. On
being heated, these change into yellow rhombic crystals,
isomorphous with mercuric chloride. This yellow form of mercuric
iodide is very unstable, and when cooled and triturated easily
again assumes the more stable red form. When fused, a yellow
liquid is obtained. _Mercuric cyanide_, Hg(CN)_{2}, forms one of
the most stable metallic cyanides. It is obtained by dissolving
mercuric oxide in prussic acid, and by boiling Prussian blue with
water and mercuric oxide, ferric oxide being then obtained in the
precipitate. Mercuric cyanide is a colourless crystalline
substance, soluble in water, and distinguished by its great
stability; sulphuric acid does not liberate prussic acid from it,
and even caustic potash does not remove the cyanogen (a complex
salt is probably produced), but the halogen acids disengage HCN.
Like the chloride, it combines with mercuric oxide, forming the
oxycyanide, Hg_{2}O(CN)_{2}, and it shows a very marked tendency
to form double compounds--for example, K_{2}Hg(CN)_{4}. The alkali
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