The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
chlorides and iodides form similar compounds--for instance, the
salt HgKI(CN)_{2} crystallises very well, and is produced by
directly mixing solutions of potassium iodide and mercuric
cyanide.
Wells (1889) and Vare obtained and investigated many such double
salts, and showed the possibility of the formation, not only of
HgCl_{2}MCl and HgCl_{2}2MCl where M is a metal of the
alkalis--for example, Cs--but also of HgCl_{2}3MCl,2(HgCl_{2})MCl,
and in general _n_HgX_{2}_m_MX, where X stands for various
haloids.
Mercury has a remarkable power of forming very unstable compounds with
ammonia, in which the mercury replaces the hydrogen, and, if a mercuric
compound be taken, its atom occupies the place of two atoms of the
hydrogen in the ammonia. Thus Plantamour and Hirtzel showed that
precipitated mercuric oxide dried at a gentle heat, when continuously
heated (up to 100°-150°) in a stream of dry ammonia, leaves a brown
powder of _mercuric nitride_, N_{2}Hg_{3}, according to the equation 3HgO
+ 2NH_{3} = N_{2}Hg_{3} + 3H_{2}O.[24 bis] This substance, which is
attacked by water, acids, and alkalis (giving a white powder), is very
explosive when struck or rubbed, evolving nitrogen, proving that the bond
between the mercury and the nitrogen is very feeble.[25] By the action of
liquefied ammonia on yellow mercuric oxide Weitz also obtained an
explosive compound, dimercurammonium hydroxide, N_{2}Hg_{4}O, which
corresponds with an ammonium oxide, (NH_{4})_{2}O, in which the whole of
the hydrogen is replaced by mercury. A solution of ammonia reacts with
mercuric oxide, forming the hydroxide, NHg_{2}.OH, to which a whole
series of salts, NHg_{2}X, correspond; these are generally insoluble in
water and capable of decomposing with an explosion. But salts of the same
type, but with one atom of mercury, NH_{2}HgX, are more frequently and
more easily formed; they were principally studied by Kane, although known
much earlier. Thus, if ammonia be added to a solution of corrosive
sublimate (or, still better, in reverse order), a precipitate is obtained
known as white precipitate (_Mercurius præcipitatus albus_) or
_mercurammonium chloride_, NH_{2}HgCl, which may also be regarded not
only as sal-ammoniac with the substitution of H_{2} by mercury, but also
as HgX_{2}, where one X represents Cl and the other X represents the
ammonia radicle, HgCl_{2} + 2NH_{3} = NH_{2}.HgCl + NH_{4}Cl. When
heated, mercurammonium chloride decomposes, yielding mercurous chloride;
when heated with dry hydrochloric acid it forms ammonium chloride and
mercuric chloride. Other simple and double salts of mercurammonium,
NH_{2}HgX, are also known. Pici (1890) showed that all the compounds
HgH_{2}NX may be regarded as compounds of the above-named Hg_{2}NX with
NH_{4}X because their sum equals 2HgH_{2}X.[25 bis]
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