The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
between the sodium and the mercury is weak, just like the connection
between mercury and many other elements--for instance, nitrogen. Mercury
directly and easily dissolves potassium, sodium, zinc, cadmium, tin,
gold, bismuth, lead, &c., and from such solutions or alloys it is in most
cases easy to extract definite compounds--thus, for instance, the
compounds of mercury and silver have the compositions HgAg and
Ag_{2}Hg_{3}. Objects made of copper when rubbed with mercury become
covered with a white coating of that metal, which slowly forms an
amalgam; silver acts in the same way, but more slowly, and platinum
combines with mercury with still greater difficulty. This metal only
readily forms an amalgam when in the form of a fine powder. If salts of
platinum in solution are poured on to an amalgam of sodium, the latter
element reduces the platinum, and the platinum separated is dissolved by
the mercury. Almost all metals readily form amalgams if their solutions
are decomposed by a galvanic current, where mercury forms the negative
pole. In this way an amalgam may even be made with iron, although iron in
a mass does not dissolve in mercury. Some amalgams are found in
nature--for instance, silver amalgams. Amalgams are used in considerable
quantities in the arts. Thus the solubility of silver in mercury is taken
advantage of for extracting that metal from the ore by means of
amalgamation, and for silvering by fire. The same is the case with gold.
Tin amalgam, which is incapable of crystallising and is obtained by
dissolving tin in mercury, composes the brilliant coating of ordinary
looking-glasses, which is made to adhere to the surface of the polished
glass by simply pressing by mechanical means sheets of tin foil bathed in
mercury on to the cleansed surface of the glass.[26] (_See_ 'The Nature
of Amalgams,' by W. L. Dudley; Toronto, 1889.)
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