The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[26] I consider it appropriate here to call attention to the want of an
element (ekacadmium) between cadmium and mercury in the periodic
system (Chapter XV.) But as in the ninth series there is not a
single known element, it may be that this series is entirely
composed of elements incapable of existing under present
conditions. However, until this is proved in one way or another,
it may be concluded that the properties of ekacadmium will be
between those of cadmium and mercury. It ought to have an atomic
weight of about 155, to form an oxide EcO, a slightly stable oxide
Ec_{2}O. Both ought to be feeble bases, easily forming double and
basic salts. The volume of the oxide will be nearly 17·5, because
the volume of cadmium oxide is about 16, and that of mercuric
oxide 19. Therefore the density of the oxide will approach 171 ÷
17·5 = 9·7. The metal ought to be easily fusible, oxidising when
heated, of a grey colour, with a specific volume, about 14
(cadmium = 13, mercury = 15), and, therefore, its specific gravity
(155 ÷ 14) will nearly = 11. Such a metal is unknown. But in 1879
Dahl, in Norway, discovered in the island of Oterö, not far from
Kragerö, in a vein of Iceland spar in a nickel mine, traces of a
new metal which he called norwegium, and which presented a certain
resemblance to ekacadmium. Perfect purity of the metal was not
attained, and therefore the properties ascribed to norwegium must
be regarded as approximate, and likely to undergo considerable
alteration on further study. A solution of the roasted mineral in
acid was twice precipitated by sulphuretted hydrogen, and again
ignited; the oxide obtained was easily reduced. When the metal was
dissolved in hydrochloric acid largely diluted with water, and the
solution boiled, the basic salt was precipitated, and thus freed
from the copper which remained in the solution. The reduced metal
had a density 9·44, and easily oxidised. If the composition NgO be
assigned to the oxide, then Ng = 145·9. It fused at 254°; the
hydroxide was soluble in alkalis and potassium carbonate. In any
case, if norwegium is not a mixture of other metals, it belongs to
the uneven series, because the heavy metals of the even series are
not easily reducible. Brauner thinks that norwegium oxide is
Ng_{2}O_{3}, the atom Ng = 219, and places it in Group VI., series
11, but then the feebly acid higher oxide, NgO_{3}, ought to be
formed.
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