The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Boron trioxide or boric anhydride enters into the composition of many
minerals, in the majority of cases in small quantities as an isomorphous
admixture, not replacing acids but bases, and most frequently alumina
(Al_{2}O_{3}), for as a rule the amount of alumina decreases as that of
the boric anhydride increases in them. This substitution is explained by
the similarity between the atomic composition of the oxides of aluminium
(alumina) and boron. The subdivision of oxides into basic and acid can in
no way be sharply defined, and here we meet with the most conclusive
proof of the fact, for the oxides of boron and aluminium belong to the
number of intermediate oxides, closely approaching the limit separating
the basic from the acid oxides. Their type (Chapter XV.) R_{2}O_{3} is
intermediate between those of the basic oxides R_{2}O and RO and those of
the acid oxides R_{2}O_{5} and RO_{3}. If we turn our attention to the
chlorides, we remark that lithium chloride is soluble in water, is not
volatile, and is not decomposed by water; the chlorides of beryllium and
magnesium are more volatile, and although not entirely, still are
decomposed by water; whilst the chlorides of boron and aluminium are
still more volatile and are decomposed by water. Thus the position of
boron and aluminium in the series of the other elements is clearly
defined by their atomic weights, and shows us that we must not expect any
new and distinct functions in these elements.
Boron was originally known in the form of sodium borate,
Na_{2}B_{4}O_{7},10H_{2}O, or _borax_, or _tincal_, which was exported
from Asia, where it is met with in solution in certain lakes of Thibet;
it has also been discovered in California and Nevada, U.S.A.[1] Boric
acid was afterwards found in sea-water and in certain mineral springs.[2]
Its presence may be discovered by means of the green coloration which it
communicates to the flame of alcohol, which is capable of dissolving free
boric acid.[3] Many of the boron compounds employed in the arts are
obtained from the impure boric acid which is extracted in Tuscany from
the so-called _suffioni_. In these localities, which present the remains
of volcanic action, steam mixed with nitrogen, hydrogen sulphide, small
quantities of boric acid, ammonia, and other substances, issue from the
earth.[3 bis] The boric acid partially volatilises with the steam, for if
a solution of boric acid be boiled, the distillate will always contain a
certain amount of this substance.[4]
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