The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[1] Borax is either directly obtained from lakes (the American lakes
give about 2,000 tons and the lakes of Thibet about 1,000 tons per
annum), or by heating native calcium borate (_see_ Note 2) with
sodium carbonate (about 4,000 tons per annum), or it is obtained
(up to 2,000 tons) from the Tuscan impure boric acid and sodium
carbonate (carbonic anhydride is evolved). Borax gives
supersaturated solutions with comparative ease (Gernez), from which
it crystallises, both at the ordinary and higher temperatures, in
octahedra, containing Na_{2}B_{4}O_{7},5H_{2}O. Its sp. gr. is
1·81. But if the crystallisation proceeds in open vessels, then at
temperatures below 56°, the ordinary prismatic crystallo-hydrate
B_{4}Na_{2}O_{7},10H_{2}O is obtained. Its sp. gr. is 1·71, it
effloresces in dry air at the ordinary temperature, and at 0° 100
parts of water dissolve about 8 parts of this crystallo-hydrate, at
50° 27 parts, and at 100° 201 parts. Borax fuses when heated, loses
its water and gives an anhydrous salt which at a red heat fuses
into a mobile liquid and solidifies into a transparent amorphous
_glass_ (sp. gr. 2·37), which before hardening acquires the pasty
condition peculiar to common molten glass. Molten borax dissolves
many oxides and on solidifying acquires characteristic tints with
the different oxides; thus oxide of cobalt gives a dark blue glass,
nickel a yellow, chromium a green, manganese an amethyst, uranium a
bright yellow, &c. Owing to its fusibility and property of
dissolving oxides, borax is employed in soldering and brazing
metals. Borax frequently enters into the composition of strass and
fusible glasses.
[2] We may mention the following among the minerals which contain
boron: calcium borate, (CaO)_{3}(B_{2}O_{3})(H_{2}O)_{6}, found and
extracted in Asia Minor, near Brusa; _boracite_ (stassfurtite),
(MgO)_{6}(B_{2}O_{3})_{8},MgCl_{2}, at Stassfurt, in the regular
system, large crystals and amorphous masses (specific gravity
2·95), used in the arts; _ereméeffite_ (Damour), AlBO_{3} or
Al_{2}O_{3}B_{2}O_{3}, found in the Adulchalonsk mountains in
colourless, transparent prisms (specific gravity 3·28) resembling
apatite; _datholite_, (CaO)_{2}(SiO_{2})_{2}B_{2}O_{3},H_{2}O; and
ulksite, or the boron-sodium carbonate from which a large quantity
of borax is now extracted in America (Note 1). As much as 10 p.c.
of boric anhydride sometimes enters into the composition of
tourmalin and axinite.
[3] This green coloration is best seen by taking an alcoholic solution
of volatile ethyl borate, which is easily obtained by the action of
boron chloride on alcohol.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account