The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[3 bis] P. Chigeffsky showed in 1884 (at Geneva) that in the
evaporation of saline solutions many salts are carried off by the
vapour--for instance, if a solution of potash containing about
17-20 grams of K_{2}CO_{3} per litre be boiled, about 5 milligrams
of salt are carried off for every litre of water evaporated. With
Li_{2}CO_{3} the amount of salt carried over is infinitesimal, and
with Na_{2}CO_{3} it is half that given by K_{2}CO_{3}. The
volatilisation of B_{2}O_{3} under these circumstances is
incomparably greater--for instance, when a solution containing 14
grams of B_{2}O_{3} per litre is boiled, every litre of water
evaporated carries over about 350 milligrams of B_{2}O_{3}. When
Chigeffsky passed steam through a tube containing B_{2}O_{3} at
400°, it carried over so much of this substance that the flame of a
Bunsen's burner into which the steam was led gave a distinct green
coloration; but when, instead of steam, air was passed through the
tube there was no coloration whatever. By placing a tube with a
cold surface in steam containing B_{2}O_{3}, Chigeffsky obtained a
crystalline deposit of the hydrate B(OH)_{3} on the surface of the
tube. Besides this, he found that the amount of B_{2}O_{3} carried
over by steam increases with the temperature, and that crystals of
B(OH)_{3} placed in an atmosphere of steam (although perfectly
still) volatilise, which shows that this is not a matter of
mechanical transfer, but is based on the capacity of B_{2}O_{3} and
B(OH)_{3} to pass into a state of vapour in an atmosphere of steam.
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