The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Up to a certain point, it is found that old limes unhair much more
readily, and have a greater softening effect than new ones, which is
often advantageous for dressing goods; though for sole leather, where
weight and firmness are of primary importance, the use of stale limes
must be kept within the narrowest limits. In the finer leathers also,
such as kid and moroccos and coloured calf, where a sound and glossy
grain is desired, the effects mentioned are generally better obtained in
other ways, such as by the use of sulphides. On East India kips and
other dried hides, which are difficult to soften, and which have great
power of resistance to the action of lime, old limes are distinctly
useful, but, even there, there are limits which should not be passed.
Probably no lime ought to be allowed to go for more than three months at
the outside limit without at least a partial change of liquor, and the
system of allowing all the limes in a yard to run for twelve months, and
then cleaning them all together, is almost the worst which can be
planned. A very much better way is to clean the limes in regular
rotation, using, if desired, a portion of the old liquor in making the
new lime, so as to avoid a too sudden transition. The old liquor is
valuable, if at all, for the ammonia and organic matter which it
contains, as the amount of lime in solution is not worth considering.
The ammonia considerably increases the solvent and unhairing power,
while swelling the hide less than an equivalent amount of lime. In some
cases it may be desirable to add ammonia artificially for this purpose.
In this case it will be cheaper and more convenient to add it in the
form of ammonium sulphate than as liquid ammonia. If it be desired to
retain ammonia, the lime should be kept covered. Very old limes
containing excess of ammonia and lime, sometimes in hot weather cause a
transparent swelling of the goods, with destruction of the fibrous
texture.[74] The writer has observed a similar phenomenon in very weak
and old limes strengthened with sulphides, in which hide was left
experimentally for several weeks. The principal effect of the dissolved
animal matter is to enable bacteria to thrive in it, which they will not
do in a fresh lime, but putrid limes probably also contain liquefying
ferments produced by the bacteria present (p. 17), and which dissolve
hide. Eitner has published researches on the amount of hide-substance
dissolved by limes,[75] in which he shows that the loss of substance in
liming sufficiently to unhair is materially greater in old limes than in
fresh ones, although during the first two days of liming the new limes
are decidedly the most active. As he remarks, this justifies the wisdom
of the method, now largely adopted, of working limes in shifts, and
beginning the operation in old limes and completing it in fresh ones.
(See also p. 131.)
[74] Gerber, 1884, pp. 150, 184.
[75] Gerber, 1895, pp. 157-9, 169-72.
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