The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Boric (boracic) acid, though used to a slight extent for a number of
years past, has recently come much into favour as a deliming agent, for
which purpose it is in many respects particularly suitable. Sole-leather
may be improved in colour by giving a short bath in 1¹⁄₂-2 per cent.
boric acid solution to remove surface-lime. In this case the acid is
best applied just before the hide enters the suspenders. Boric acid may
also be suitably employed on hides which have been bated. It then acts
as a drench and removes traces of lime still left in the hides, so that
the liquors have a more even effect on them. Experience has shown that
the skins should never be allowed to lie for any length of time in the
boric acid solution in a motionless condition, as this tends to produce
patches of partially delimed skin, which cause irregular colour. It is
best to keep the skins in fairly constant motion in a paddle or by
frequent handling. Boric acid has considerable influence in preventing
drawn grain in the early liquors, but if it gets into the forward
liquors it renders the leather loose and light (cp. p. 229, and L.I.L.B.
p. 37).
Borax has also been suggested as a deliming agent, and as it is
chemically an acid salt, it has naturally some deliming effect, but it
cannot compare with boric acid in either price or efficiency.
Both boric acid and borax are antiseptics (see p. 25).
In the employment of either sulphuric, boric, or any other acid forming
calcium salts of limited solubility, it must be borne in mind that if
the solution is repeatedly re-strengthened, it will become saturated
with the lime-salt, and although the acid will still combine with the
lime and render it neutral, it will no longer remove it from the hide.
Under these conditions, sulphuric acid may cause the deposition of
crystalline calcium sulphate in minute nodules between the fibres.
Calcium borate may be similarly deposited, and has the further
disadvantage of becoming decomposed by the tanning liquors, which form
dark compounds with the lime. In using sulphuric acid alone it is
therefore best to renew the water each time. When it is used in
conjunction with some other acid, forming very soluble lime salts, this
danger is not to be apprehended, while oxalic acid precipitates the lime
almost completely from the solution.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account