The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
It is to be borne in mind that in all cases of using acids, any
carbonate of lime present on the pit sides or elsewhere will be
decomposed, and the carbonic acid will become dissolved in the liquor,
and unless acid is used in sufficient quantity to remove the whole of
the lime, may tend to fix the remainder as carbonate. In the case of
dressing leather there is less danger of this, as warm water is
generally used, in which little carbonic acid dissolves. It is probable
that some of the coal-tar acids which have been advertised for bating
dressing leather might be advantageously employed for sole. Hauff’s
“anticalcium” (see pp. 29, 163), would appear to be very suitable for
this purpose, and if the liquor were regenerated by the addition of
sufficient sulphuric acid to neutralise the lime dissolved from the
hide, might be used repeatedly, and would not then prove expensive;
while its sterilising power would be very advantageous to the proper
swelling of the butts in the handlers, since nothing tends to check
plumping so much as putrefactive action.
Turning from sole to dressing leather, mineral acids are very
successfully employed for “pulling down,” the goods being thrown into a
paddle containing warm water of about 30°-35° C., and the calculated
quantity of sulphuric or hydrochloric acid, previously largely diluted
with water, is then added in two or three successive portions at
intervals of perhaps ten minutes. The acid must in no case be sufficient
to neutralise quite the whole of the lime. Goods treated in this way can
be further bated, puered, or drenched as required by the ordinary
methods, if they are not sufficiently soft. If too much acid has been
used, and the skins show signs of swelling, they may be brought down by
the addition of a little ammonia, borax, or even soda.
Public-domain text, read in full here on John Shaqi.
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