The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
In many cases the addition of salt in small quantity to the acid liquor
will tend to deplete the hides, and at the same time prevent any
injurious action of the acid. Ammonium chloride may also be used with
advantage (see p. 159). A solution containing about 15 per cent. of salt
and 0·3 per cent. of sulphuric acid, with some molasses, has been a good
deal used in the States as a bate, and seems to answer well on some
classes of goods, but the acid and salt are apt, ultimately, to find
their way into the liquors and destroy tannin. The process is well
suited for chrome-leather, and may also be usefully applied in cases
where goods have become “wind-blasted” or otherwise impregnated with
carbonate of lime, since in presence of salt the acid can be used in
sufficient excess to dissolve the carbonate. Vegetable acids may, of
course, be used in conjunction with salt in the same way. The salt does
not neutralise the acid, but simply controls the swelling of the skin,
and if acid has been used in any material excess, the first part of the
tanning must be done in salted liquors, or the acid neutralised with
ammonia, sodium carbonate, or chalk, previous to tanning, as, otherwise,
the goods will plump up in the liquors, and be tender when tanned (cp.
p. 91).
Lactic acid has recently come largely into use as a deliming agent. It
is best known as the acid which gives a characteristic taste to sour
milk, and is the chief product of the lactic ferment. It may be very
successfully used for neutralising the lime left in the skins after the
depilation, but, if used in excess, it tends to plump or swell the
leather very strongly, being one of the best plumping agents known. When
used for deliming, a solution of 2 lbs. in 100 gallons is very suitable.
It may, in many cases, be substituted for the bran-drench with
advantage, and is much more rapid and less dangerous in hot weather, but
the effect is not in all respects identical.[89]
[89] On the manufacture of lactic acid by fermentation, see Claflin,
Journ. Soc. Chem. Ind., 1897, p. 516. Campbell states that practically
pure cultures of the lactic bacteria are obtained by continued culture
in milk. These cultures employed as a ferment for drenches have given
good results in the Yorkshire College Experimental Tannery.
When lactic acid is used for bating, or drenching, the operation should
always be conducted in a paddle, and the liquid works more
satisfactorily if it is at a temperature of 30-35° C. As regards cost,
it will be found that in practice it is not appreciably more expensive
than dung or bran. About an hour’s paddling will generally suffice, if
the right quantity of acid has been used, but in some cases it is best
to add the acid in several portions and take more time.
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