The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
“Cresotinic acid,” a mixture of impure acids obtained from cresols in
the same way as salicylic acid is manufactured from pure phenol, was
introduced as a bate and unhairing and deliming agent by J. Hauff, of
Feuerbach.[91] He also claims the use of hydrochloric acid to liberate
the acid after it has been combined with lime in the deliming process.
It is only soluble to the extent of about 1 in 800 of water, so that,
even if used in excess, no dangerously strong solution is formed, but it
has a tendency to slightly swell, and somewhat harden, the hides or
skins, so that it is perhaps more suitable for sole than dressing
leather. It has also powerful disinfectant properties (see p. 29).[92]
[91] Eng. Pat. 14,889, 1888.
[92] Compare also Journ. Soc. Chem. Ind., 1889, p. 954.
Hauff states that a solution of 18 lb. of cresotinic acid in 500 gallons
of water at 30° C. will bate one lot of 50 heavy hides, and that the
same liquor may be used continuously, by adding 4-5 lb. more cresotinic
acid for each successive 50 hides. For bating glove-leather, Hauff
recommends the use of 5 kilos. cresotinic acid dissolved in 1000 liters
of warm water for every 500 kilos. of wet skins, to which is added
ammonia nearly sufficient to neutralise the cresotinic acid, leaving the
solution still slightly acid to litmus paper; and he also advises the
addition of 5 kilos. of ammonium chloride or sulphate. The goods are
paddled in this solution for about half an hour.
“Oxynaphthoic acid,” the corresponding mixed acids of the naphthols (p.
30), has also been patented by Hauff as a bate, since cresotinic acid
sometimes acts too powerfully on light skins.[93] He mentions that
mixtures of this and cresotinic acid, or salicylic acid, may also be
used. Oxynaphthoic acid requires for its solution 20,000 to 30,000 parts
of water.
[93] Eng. Pats. 10,110 and 12,521. Journ. Soc. Chem. Ind., 1889, pp.
124, 809; 1890, p. 85.
A mixture of the α and β mono- and di-sulphonic acids of naphthalene has
also been patented for bating,[94] under the name of “Acrilene bating
and puering acid.” 150 calf-skins, weighing 880 lb., were pured in a 3
per cent. solution of the α acid, and gave 266 lb. of leather as against
255 lb. from a lot of similar weight treated with hen-dung, and this
gain was more than maintained on stuffing, while the shoulders were
plumper and fuller. This patent appears to anticipate a part of Hauff’s
claim mentioned in the next paragraph.
[94] Burns and Hull, Eng. Pat. 8096, 1891; Journ. Soc. Chem. Ind.,
1892, p. 48.
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