The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
More recently Hauff has patented, under the name of “anticalcium,” a
mixture of impure sulphonic acids of various cresols and hydrocarbons.
This is cheaper than cresotinic acid, and like it, possesses
considerable antiseptic powers. One-half to one-quarter per cent.
solution will keep hides uninjured for a considerable time, but at this
strength it plumps considerably, and seems more suitable as a deliming
agent for sole-leather than as a bate for dressing-leather, though it
may replace drenching. No doubt, by the use of warm water, and avoidance
of excess of acid, skins could be pulled down satisfactorily, or the
plumping could be controlled by addition of salt, but the disinfectant
powers of the acid would render further treatment with an ordinary bate
or puer very difficult.[95]
[95] J. Hauff, Eng. Pat. 22,546, 1894; Journ. Soc. Chem. Ind., 1895,
p. 170, Gerber, 1895, p. 133.
The “C. T. Bate,” manufactured by the Martin Dennis Chrome Company, is
of a very similar character; and is in the form of a greyish crystalline
paste, consisting mainly of sulphonic acids of naphthalene and probably
other hydrocarbons. It is very possibly made by sulphonating
coal-creasote oils, which contain much naphthalene and phenanthrene. The
following directions are given by the company for its use.
“1. After unhairing and fleshing from the lime, the skins should be
thoroughly washed with water (preferably warm) so as to remove as much
lime as possible.
2. If, in the liming process, the sulphide of sodium is used in
combination with the lime, it will render the lime more soluble and
therefore more easily removed with water.
3. The more completely the skins are cleansed with warm water the less
will be the quantity of bate required.
4. After washing, the skins should be thoroughly worked on the beam,
especially on the grain.
5. A solution of C. T. Bate is now prepared in the proportion of from
one-half pound to one pound of bate in 100 gallons of warm water (90°
F.). In making the solution do not have the water over 140° F. Under no
circumstances boil it.
6. If the hides or skins have been treated as above indicated, one pound
of bate should be sufficient for 400 pounds wet hide, washed from the
limes. The hides or skins are placed in the bating solution and worked
for an hour. They are then allowed to rest in the solution with
occasional stirring for some hours or over night.
7. The length of time that the bating should continue will depend upon
the degree of softness and pliability required in the leather. For
instance, for sole-leather fifteen minutes is sufficient; for satin
leather thirty minutes; for glove-leathers four to six hours or even
longer.
8. On removing the skins from the bating solution it is sometimes
desirable, especially for the finer grades of leather, to wash them in
warm water and again work them over the beam. They are then ready to be
placed in the tanning liquors.
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