The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
It does not fall within the scope of this book to describe in detail the
working methods for the production of the different kinds of chrome
leather, but a few precautions common to all forms of the process may be
named. It is not absolutely important in all cases that goods should be
completely freed from lime before chrome-tannage, but in this case a
sufficiency of acid must be allowed in the first bath to neutralise the
lime introduced. Pretty thorough liming is generally advisable, to plump
and separate the fibres, but as a rule the bating or puering of goods
for chroming should not be excessive,[118] but should be planned not to
remove more than is absolutely necessary of the hide-substance, as the
chrome tannage is in its nature soft and light, and does not lend itself
to artificial fillings, such as the flour and egg-yolk of the calf-kid
process. Skins are sometimes freed from lime by “pickling” (p. 89), and
pickled skins may be chromed without depickling, which will be done by
the dichromate, but in this case the acid contained in the skins must be
considered in the composition of the chroming bath. Skins, indeed, which
are pickled with a sufficiency of acid may be chromed in a neutral
dichromate bath, and this is sometimes a convenient mode of procedure.
To prevent drawing of the grain during tanning, skins not unfrequently
receive a preliminary tannage with alum, or sulphate of alumina, and
these materials, together with salt, may be introduced into the chroming
bath, in which case they will liberate a portion of the chromic acid, as
has been mentioned in connection with the Heinzerling process. Alum,
chrome-alum, and acid salts, such as sodium bisulphate, may be
substituted for the acid in the chrome bath, but organic acids must not
be used, as they would reduce the chromic acid. The quantity of free
chromic acid in the chrome bath is of the most vital importance to
success, as it, and not the dichromate (which may be present in
considerable excess), regulates the amount of chrome taken up by the
skin, and the subsequent degree of tannage. It is very possible to
injure leather by overchroming, rendering it rough, harsh and even
tender. If a bath containing excess of bichromate is to be
re-strengthened, it may be assumed as a rule that all the free chromic
acid has been absorbed by the skins, and while it is merely necessary to
restore the strength of the dichromate to its original amount, the full
quantity of acid must be used which would be required in preparing a new
bath. Where, as in Eitner’s acid chrome bath, the whole of the chromic
acid is liberated, the bath may be exhausted by a second pack of skins.
Many tanners, in order to avoid the complications of remaking a bath,
run away their chrome liquors after once using, containing all the
excess of dichromate which has been used. With proper chemical control,
this should not be necessary, and is objectionable, not only from its
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