The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
wastefulness, but on account of the very poisonous character of the
unreduced bichromate. Even weak dichromate solutions, especially if
warm, are liable to cause painful and obstinate eruptions on the hands,
but this rarely occurs to tanners, as the poisonous action of the
solution is removed on reduction. It is well, however, to arrange that
men who handle skins in the chrome bath, should subsequently also work
in the reducing bath. Methods of analysis of used chrome liquors are
given, L.I.L.B., pp. 142 _et seq._ Those for the determination of
acidity are not however easily applicable in the presence of alum and
salts of chromic oxide.
[118] Goat-skins for glacé kid need thorough puering to produce a
smooth grain.
The skins, on coming from the chroming bath may be allowed to lie for
some time without serious injury, but should be carefully protected from
the action of light, which reduces the chrome at the expense of the
skin, and renders the subsequent tannage irregular. It is found that
skins, if brought into a weak or neutral reducing bath, are apt to
“bleed” or lose chromic acid, which is reduced wastefully in the bath.
On the other hand a strong “hypo” bath is apt to draw the grain and
contract the skins, owing to the tannage taking place too suddenly. A
somewhat strong “hypo” bath is therefore often employed as a preparatory
“dip,” the skins being simply drawn through it to fix the chrome on the
surface, piled on a “horse” and subsequently reduced in a bath of
ordinary strength. The tendency to bleed is lessened, but at the expense
of the pelt, by the reduction which takes place if the skins are allowed
to lie overnight in the chromed state. Eitner states that skins chromed
in an acid bath (i.e. where the whole of the chromic acid is in a free
state) show little tendency to bleed. After reduction, the skins are
well washed with warm water, and their subsequent treatment is the same
as that of skins tanned by the one-bath process, which is subsequently
described (see p. 211).
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