The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Naturally in practical work, the reduction cannot be made to proceed
rigidly in the definite steps described by Eitner on p. 206, but all go
on in different proportions together, though by supplying the acid in
proper quantities, and at proper intervals, they may be made in the main
to follow in the given order. Both on this account, and because neither
the exact amount of chromic acid in the skins, nor the sulphurous acid
lost by escape into the air can be exactly determined, the reduction
cannot be conducted on theoretical principles, but the best conditions
must be empirically determined. Eitner states that 12 parts of
thiosulphate dissolved in 400 parts of water, and 6 parts of (40 per
cent.) hydrochloric acid are sufficient for 4 parts of bichromate per
100 of wet pelt employed in the chrome bath, of which not more than
one-half to two-thirds is absorbed; and that if equal parts of
bichromate and acid are employed in chroming, the acid used in reducing
may be lessened to 5 parts. In this case it must not be forgotten, that
if the partially exhausted chrome-bath is used for a second pack of
skins, which are afterwards finished in a bath of full strength, nearly
the whole quantity of bichromate used in making up one bath will be
absorbed by the skins. The amount of acid consumed in reduction will be
greater, the more rapidly it is added, owing to increased escape of
sulphurous acid. It is better to add the acid, previously diluted with
water, in 8 or 10 successive portions, more rapidly at first, and more
slowly during the latter half of the operation, each portion of acid
being added as soon as no further change of colour appears to be caused
by that already given. These changes are the more rapid the lighter the
goods. The colour darkens at first to olive-brown, then gradually
becomes green, and finally blue, and when this colour is uniform
throughout the thickness of the goods, no further acid need be added.
For goods which have been chromed in an acid bath, Eitner states that no
acid will be needed for the first twenty to thirty minutes. It is
important to have a sufficient excess of thiosulphate in the bath when
reduction is complete, in which case the goods may be left for some
hours or overnight in the bath, to complete “neutralisation,” but Eitner
prefers to use a fresh bath of 1¹⁄₂ parts of thiosulphate in 400 parts
of water for this purpose, the bath being used, after settling, for
making up the reduction bath for the next lot of goods, for which 1¹⁄₂
parts less thiosulphate is used. The goods must be kept in motion during
reduction, either in a drum or a covered paddle.
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