The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
It is probable that one of the great causes of difference between
“one-bath” and “two-bath” leathers is the presence of free sulphur in
the latter. This may also be introduced into “one-bath” leather, by
treating it in the wet chromed state, without washing out the chrome
liquor, with excess of a solution of hyposulphite, or of an alkaline
polysulphide, which at the same time will neutralise the skin. The more
acid the chrome liquor, the greater the quantity of sulphur which will
be introduced. The simplest means of distinguishing “two-bath” from
“one-bath” tannages is to test for the presence of sulphur, by wrapping
up a silver coin, with a piece of the leather in paper, and leaving the
parcel for an hour in the water-oven, or some other warm place, when
the presence of sulphur will be shown by the blackening of the coin. Of
course a sulphurised “one-bath” leather will give the same reaction.
The leather must now be dyed and fat-liquored. Which of these two
operations should be first undertaken will depend on circumstances. Most
leathers dye more easily before fat-liquoring, but as many dyes are
soluble in the alkaline fat-liquor, a good deal of colour is often lost.
This may be compensated by dissolving a suitable aniline (acid) colour
in the fat-liquor. “Bluebacking” is generally done before fat-liquoring
by drumming with methyl-violet, or some other aniline colour (with or
without logwood, which gives alone a very dark violet). Any shaving or
splitting required must of course be done before bluebacking.
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