The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The fat-liquor is an emulsion of soap and oil, which for chrome leather
should be as neutral as possible, if the neutralising has been thorough;
but if any acid be left on the skins, a neutral fat-liquor will be
precipitated as a greasy mass. This can sometimes be remedied by the
addition of a little ammonia or borax, or by re-fat-liquoring with soap
solution only, but if the washing of the skins has been incomplete, and
soluble chrome-salts remain, the mischief is almost irretrievable, as
sticky chrome-soaps are formed, often coloured with the aniline violet,
which adhere to the skins, and which can scarcely be removed by any
solvent which does not injure the leather. As regards the soaps and oils
used, there is considerable latitude: 1¹⁄₂ per cent. of castor-oil soap,
and ³⁄₄ per cent. of castor or olive oil on the wet weight of the pelt
has done good service in my hands, but many manufacturers employ soft
soaps, curd soaps, etc., with castor, olive, cod or neatsfoot oil, and
sometimes sod-oil or degras. Eitner considers olive-oil and olive-oil
potash soap the most suitable, and particularly warns against the use
either of drying oils or of oils containing tallow (such as neatsfoot),
which are not only apt to cause a white efflorescence, but to give the
leather a disagreeable rancid smell. Fish-oils are unsuitable, but
mineral oils are often useful constituents of fat-liquors. Wool-fat also
makes a good fat-liquor, but is unsuitable for goods which are to be
glazed. “Turkey-red oil” (which is sulphated castor) may be used as a
fat-liquor, simply mixed with warm water, without soap, and has been
recommended where delicate colours are to be dyed after fat-liquoring;
but it is said to have an unsatisfactory after-effect, hardening and
tendering the leather. Some soaps made from the saponifiable part of
wool grease, such as “Lanosoap,” also act well in conjunction with
olive, castor, or other oils. Where leather is to be glazed, the amount
of fat-liquoring must be kept very moderate. Fat-liquors should be
thoroughly emulsified, and are generally used warm. They penetrate
better if the leather is partially dried by sleeking out, or pressing,
or cautious “samming,” but the leather must not be completely dried out
before fat-liquoring and dyeing, unless it has been previously treated
with glycerine, glucose, treacle or some deliquescent salt, which will
enable it to be wet back. Chrome leathers are not “waterproof,” as has
often been stated, unless rendered so by treatment with soaps and
greases, and are apparently easily wetted, but the fibre will no longer
absorb water after thorough drying, and consequently will neither dye
nor stuff satisfactorily. In order to enable chrome leather to be kept
in an undyed condition, glycerine or syrup is sometimes mixed with the
fat-liquor, but as the watery portion of this is not generally
completely absorbed, the process is somewhat wasteful. Mr. M. C. Lamb
Public-domain text, read in full here on John Shaqi.
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