The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
avoids this difficulty by applying a solution of glycerine to the
grain-side with a sponge after fat-liquoring. In this case the leather
may be dried sufficiently for staking or shaving without risk.
Chrome leather can be dyed by many of the acid aniline colours without a
mordant. Basic colours are only fixed when the leather has been first
prepared with a vegetable tannin, gambier, or a mixture of gambier and
sumach being the most suitable. Considerable care must be employed in
the application of tannins to chrome leather, as they have a tendency to
harden it and diminish its stretch, or even to render it tender, but
traces of tannin in the dye probably facilitate glazing. Before dyeing,
it is advantageous to fix the tannin with tartar emetic, or for browns
and yellows, with titanium potassium oxalate solution, which itself
gives a good yellow-brown with tannin. In place of employing the tannin
and titanium salt in two separate baths, they may be combined, using a
weight of the gambier or tanning extract (oakwood, chestnut, etc.) about
equal to that of the titanium salt, or titanium tanno-oxalate solution
may be used. Chrome leather may be dyed with the various dye-woods,
which are mordanted by the chromium present, but the colours are mostly
dull, that of logwood being nearly black. A good black of a very
permanent character is obtained by dyeing with logwood, and saddening
with a hot solution of titanium oxalate in the drum. A little iron-alum
added to the chrome liquor in tanning will facilitate dyeing the skins
black with logwood and help it to penetrate through the leather, which
is sometimes desired. Several aniline blacks, and notably the
“corvolines” of the Badische Anilin und Soda Fabrik, Casella’s “leather
black C,” and Claus & Rée’s chrome-black give very satisfactory blacks
by brushing or dyeing.
Chrome skins may be glazed in the ordinary way with blood or albumen
mixtures under glass or agate, but require good pressure and repeated
seasonings and glazings, and much care is required in fat-liquoring. The
glazing is often assisted by the previous application of barberry juice
(épine vinette) or of lactic or tartaric acid solution with a trace of
sugar. Much of the difficulty which has been experienced in glazing
chrome leathers is due either to the natural fat of the skin, or to oils
used in fat-liquoring in excessive quantity or of unsuitable character.
CHAPTER XVI.
_PRINCIPLES OF THE VEGETABLE TANNING PROCESSES._
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