The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
replaced from the materials as rapidly as it is absorbed by the leather,
while, when liquors or extracts only are used, the greater part of these
solidifying and weight-giving constituents remain unutilised in the
spent tanning materials. At the same time, the long “layers” afford an
opportunity for the acetic and lactic fermentations to go on which are
the principal source of the natural acidity of liquors. It must be
understood that what are called layers in England, are not to be
identified with the _Sätze_, but rather with the _Versenke_ of the
German tanner, the former being layers given in much the same manner as
was current in England 150 years ago; in which the leather, with thick
layers of tanning material between it, is laid into the empty pit, which
is afterwards filled up with liquor, often of a comparatively weak
character. In such layers, the acidification, and the solidification of
the leather both go on to a still greater degree; the acid formed,
apparently gradually penetrating to the heart of the leather-fibres, and
producing a solidity, and cheesy texture which can hardly be obtained by
layers of the English kind; which nevertheless have the advantage in
rapidity and cheapness.
[126] Journ. Soc. Chem. Ind., 1901, p. 428.
In drying sole-leather, one of the great objects which must be aimed at
is to remove the dark coloured liquor, with which the goods are
saturated, from the surface, and to prevent further portions of it from
finding their way there from the interior. If a strip of filter-paper be
allowed to rest with one end in a basin containing a little liquor, and
be placed in a draught of air, the exposed end of the paper will rapidly
become dark brown or black, the liquor which evaporates there being
constantly replaced by fresh portions sucked up by capillary attraction
from the basin. A similar action is constantly seen, when filtering
liquors through paper, if the latter be allowed to project above the
edge of the funnel. Precisely the same effect occurs, perhaps increased
by the oxidation of the tannins, on the edges and other parts of a butt
which are most exposed to draughts of air. The use of oiling the grain
is not only, to a certain extent to protect it from oxidation, but also
to check evaporation, and the consequent accumulation there of the
dark-coloured solids contained in the liquor. A very similar result is
attained by wetting the grain-side, and allowing as much of the
evaporation as possible to take place from the flesh.
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