The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
So long as tanners were restricted on the one hand, to the ordinary
methods of stuffing tanned leathers with oils and fats, and on the other
to the use of egg-yolk, which had long been common in alum-tannages,
combination-tannage remained of but secondary importance, and it was the
application of the method of “fat-liquoring” by James Kent to his
Dongola leather, which gave them the place they now possess, by
providing a cheap substitute for egg-yolk, and enabling the tanner to
obtain softness and resistance to water, without producing the greasy
feel which is common to curried leathers. The process of fat-liquoring
has already been mentioned in connection with chrome leathers, to which
it was subsequently applied, and we shall return to it, after having
given some further details of the methods of tannage.
In the first place we must consider briefly the mutual action of the
mineral and vegetable tannages on each other. It has been pointed out
by Eitner, and also mentioned (p. 339) in connection with the
decolorisation of extracts, that the addition of say ¹⁄₂ per cent. of
alum, or aluminium sulphate to tanning liquors, lightened their colour,
not only by giving a degree of acidity to the solution, but by
precipitating a portion of the less soluble and more darkly coloured
tannins. Chrome-alum, and basic chrome salts produce a similar effect,
though from their marked colour, the lightening of the solution is not
so easily observed. It is therefore advisable if these salts are to be
used in actual mixture with the vegetable tans, to allow the solution
time to subside, or to filter off the dark-coloured precipitated
matters. Larger quantities than ¹⁄₂ per cent. of the alum do not appear
materially to increase the effect just described.
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