The Principles of Leather Manufacture — John Shaqi
The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
In the “sweating” process the epidermic cells are broken down by
putrefactive organisms and their products, so that the hair becomes
loose and may then be either rubbed or scraped off. Ammonia, which is
produced during the putrefaction, has also an important solvent action,
and its presence doubtless tends to quicken the processes both of
unhairing and of destruction.
To obtain useful knowledge of the structure of any particular skin, it
is not necessary to have a very elaborate or expensive microscope, and
it is quite possible to obtain useful information merely by the use of a
good pocket lens, as for instance, in the examination of various forms
of “grain,” and the embossing of one skin to imitate another.
For further details of the manipulation and selection of the microscope,
the reader must consult L.I.L.B., pp. 234 _et seq._
CHAPTER VIII.
_THE CHEMICAL CONSTITUENTS OF SKIN._
The chemistry of the various constituents of skin is still very
imperfectly understood, but Beilstein, in his great handbook of organic
chemistry, places gelatin, albumens and keratins in the “aromatic”
series, and implies therefore that they contain the “benzene” ring. It
is at least certain that all are very complex.
The epidermis structures belong to the class of keratins, which are
closely related to coagulated albumin; while the white fibres of the
corium (or true skin) are either identical with gelatin, or only differ
from it in their molecular condition or degree of hydration. This
gelatinous tissue constitutes the bulk of the corium, but it also
contains albumen as a constituent of the lymph and blood which supply
its nourishment, keratins in the epithelial structures of the blood and
lymph vessels, and “yellow fibres,” which are perhaps allied to the
keratins, but which cannot well be isolated for analysis.
The white connective tissue of the corium is converted into gelatin
(glutin) by boiling with water. Owing to the impossibility of obtaining
unaltered hide-fibre free from the other constituents, and still more to
that of deciding to what point it should be dried to remove uncombined
water, it is impossible to prove by analysis whether its composition is
identical with that of glutin; but as the white fibre constitutes by far
the largest part of the corium, and the other constituents do not differ
largely from it in their percentage composition, an analysis of
carefully purified corium is practically identical with that of the
actual fibre. The following analyses of hide and gelatin are therefore
of interest.
The analyses of Von Schroeder and Paessler[22] are of special importance
as being the average of a large number of separate determinations.
Their nitrogen determinations are by Kjeldahl’s method. Small amounts of
ash and traces of sulphur are neglected, and probably included in the O,
which is obtained by difference.
[22] Ding. Polyt. Journ., 1893, cclxxxvii. pp. 258, 283, 300.
ANALYSES OF PURIFIED CORIUM.
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