The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The behaviour of gases and vapours has been described in some detail
because it possesses very close analogy to that of substances in
solution. The molecules of liquids are held together by attractions
which are very powerful over the short distances which separate them,
amounting in most cases to many tons per square centimeter of sectional
area, but the range over which they act is very small. In the interior
of the liquid the attractions on one side of a molecule are of course
exactly balanced by those on the opposite side, so that it is free to
move within the liquid without hindrance, but at the surface a very
small part of the force due to the attractions of the surface-layer is
unbalanced and acts as a sort of elastic skin holding the liquid
together, and is called “surface-tension.” Familiar examples of this are
found in the force which supports a drop on the end of a tube, the
possibility of laying a slightly oily needle on the surface of water
without sinking, and the ability of some flies to walk on water as if it
were covered with a sheet of india-rubber. Many liquids will mix or
dissolve in each other in any proportions, e.g. water and alcohol; the
attraction of the alcohol for the water-molecule being as great or
greater than that of alcohol for alcohol, or water for water. In other
cases, such as water and oil, or water and petroleum spirit, practically
no mixture takes place, their mutual attraction being small; and each
retains a considerable surface-tension at the points of contact, though
less than that of the free surfaces, since each exerts an attraction on
the other. There are also many intermediate cases, such as water with
chloroform, carbolic acid, or ether, in which each solvent dissolves a
portion of the other, but the two solutions do not mix, but form
separate layers. In these cases an equilibrium is attained, in which
there is just as much tendency for either of the liquids to pass into as
out of the other layer. In this there is an extraordinary resemblance to
what has been said of vapour-pressures; and the tendency to pass into
solution is often called solution-pressure; and it may be noted that
when equilibrium has been reached, not only is the solution-pressure,
but the vapour-pressure of each constituent equal in both solutions.
Like vapour-pressures, the solution-pressures usually increase with rise
of temperature, more of each constituent passing into the other, till at
last the composition of the two layers becomes identical, their
surface-tensions disappear, and complete mixture takes place. With
phenol (carbolic acid) and water this takes place at about 70° C.
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